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SHINE-ON

This is a tack free (non-wipe), shatterproof top gloss with superior shine and mirror-like finish. Shine-On can be applied over any Akzéntz gel for a flawless finish. It is easy to apply and to soak off. Like all of Akzéntz gels, Shine-On is 100% pure gel and solvent free. 

  • Adds amazing shine without yellowing over time

  • Reliable Akzéntz quality.

  • LED 30 sec. cure / UV 2 min. cure 

  • Works with any gel or acrylic

 

Anne’s Professional Opinion

“This is my favourite top coat I use almost all the time”

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X-Bond

A universal bonding gel, designed to flawlessly integrate with all of your favourite Akzéntz gel systems. X-BOND provides the ultimate bond, for even the most troublesome lifters. X-BOND is the perfect base coat for Gel Polish, Hard Gel Sculptures, Soak Off Gel systems & more.

Superior Bond 

100% pure gel

Reliable Akzéntz quality

LED 30 sec. cure / UV 2 min. Cure

 

Anne’s Professional Opinion

“My favourite base gel.  Perfect for problem lifters.”

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Marble Surface

PRODUCT
DESCRIPTIONS & SDS Sheets

LIGHTS-OUT

A quick soak-off gel applied between the colour and top coat to add a fun and long-lasting glow in the dark effect. Lights-Out comes in an easy to apply “polish” format and can be used with any gel system. 

  • Glows for hours 

  • 100% pure gel

  • Odour free and soaks off in minutes 

  • Reliable Akzéntz quality

  • LED 30 sec. cure / UV 2 min. cure

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LUXIO BUILD

Designed to create the perfect arch, fix corner breaks, and picture perfect natural nails overlays. 

 

Anne’s Professional Opinion

“Perfect If you’re wanting to create the perfect c curve on a natural nail”

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BLING ON

Thick viscosity, extra strong gel designed to keep gems, stones and embellishments securely on the nail. 

 

Anne’s Professional Opinion

“Perfect product to adhere gemstone clusters to the nail”

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OPTIONS CRYSTAL CLEAR

Stain resistant clear self-leveling builder gel that provides strength and flexibility with high gloss finish.

 

Anne’s Professional Opinion

“Super strong builder gel that can also be used as a top coat. Does not yellow the nail”

UV/LED Gel Play Paint

 

SAFETY DATA SHEET

This Safety Data Sheet complies with the Canadian Hazardous Products Regulations, the United States Occupational Safety and Health

Administration (OSHA) Hazard Communication Standard, 29 CFR 1910 (OSHA HCS), and the European Union Directives.

1. Product and Supplier Identification

1.1 Product: UV/LED Gel Play Paint

  1. 1.2  Product Use:

  2. 1.3  Producer:

    Supplier:

  3. 1.4  Emergencies (24-hour number): +1(604) 278-5851

    2. Hazards Identification

2.1 Classification of product or mixture

Note to reader: This product in an untested mixture and GHS classification is based on the classification of the ingredients and their concentrations. Proprietary ingredients do NOT exhibit any health effects not listed in this SDS.

Nail Gel

Haigh Industries Inc.,
#5 – 8118 North Fraser Way, Burnaby, B.C.
Canada, V5J 0E5

Telephone: (604) 278-5851

As above

GHS Classification:

Skin Irritation: Category 2
Eye Irritation: Category 2A
Skin Sensitization: Category 1
Specific Target Organ Toxicity, SE, Respiratory Category 3 Germ Cell Mutagenicity: Category 2
Reproductive Toxicity: Category 2

2.2 GHS Label Elements, including precautionary statements Pictogram:

 

Signal Word: Warning GHS Hazard Statements:

GHS Precautionary Statements:

H315: Causes skin irritation.
H317: May cause an allergic skin reaction.
H319: Causes serious eye irritation.
H335: May cause respiratory irritation.
H341: Suspected of causing genetic defects.
H361: Suspected of damaging fertility or the unborn child.

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UV/LED Gel Play Paint

Prevention:

Response:

P201: Obtain special instructions before use.
P202: Do not handle until all safety precautions have been read and

understood.
P261: Avoid breathing mist, vapours or spray
P264: Wash skin thoroughly after handling.
P271: Use only outdoors or in a well-ventilated area.
P272: Contaminated work clothing should not be allowed out of

the workplace.
P280: Wear protective gloves/protective clothing/eye

protection/face protection.

P302+P352: IF ON SKIN: Wash with plenty of soap and water. P304+P340: IF INHALED: Remove person to fresh air and keep

comfortable for breathing.
P305+P351+P338: IF IN EYES: Rinse cautiously with water for

several minutes. Remove contact lenses, if present and

easy to do. Continue rinsing.
P308+P313: IF exposed or concerned: Get medical advice/attention. P312: Call a POISON CENTER/doctor...if you feel unwell.
P321: Specific treatment (see Section 4).
P332+ P313: If skin irritation occurs: Get medical advice/attention. P333+P313: If skin irritation or rash occurs, get medical advice/attention P337+P313: If skin irritation or rash occurs: Get medical

advice/attention.
P362 + P364: Take off contaminated clothing and wash it before reuse.

P403+P233: Store in a well-ventilated place. Keep container tightly closed.

P405: Store locked up.

P501: Dispose of contents/container to an approved waste disposal plant.

Storage:

Disposal:

  1. 2.3  Hazards not otherwise classified (HNOC) or not covered by GHS: None

  2. 2.4  Additional Information

    Primary Routes of Entry:

    Skin Contact: Yes Skin Absorption: Yes Eye Contact: Yes Ingestion: No Inhalation: Yes

    Emergency Overview: This product contains ingredients which may cause mild eye and skin irritation in some people. For eye contact, symptoms may include a moderate burning sensation, tearing, redness, or swelling. Contact with skin may cause an allergic reaction due to prior sensitization. Local redness, rash, or itchy skin may occur in those persons with a pre-existing sensitivity or those predisposed to skin problems. In rare cases an allergic skin reaction may occur after long term contact with this product.

    Effects of Short-Term (Acute) Exposure:

    Inhalation: Due to the low volatility of this product, no significant adverse health conditions are expected to occur during the proper use of this product. In rare cases some respiratory irritation may occur.

    Skin Contact: It is expected that absorption through the skin will contribute to overall exposure. Contact with skin may cause an immediate allergic reaction in persons who may be sensitized by previous exposures. Symptoms may include an immediate rash, local redness, or itching of the skin.

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UV/LED Gel Play Paint

Eye Contact: This product is an eye irritant. Exposure to the eye may cause symptoms which include a burning sensation, tearing, redness and swelling.

Ingestion: No adverse health effects are expected if a small amount of this product is accidentally ingested.

Effects of Long-Term (Chronic) Exposure: This product contains ingredients which have been known to cause skin sensitization in some people. Sensitization may occur after prolonged or repeated exposures to this product. Prolonged contact with skin may defat tissue causing dermititis or aggravate existing skin problems.

Medical Conditions Aggravated By Exposure: Persons susceptable to skin problems may find that the use of this product will cause increased symptoms of existing skin problems.

3.1 Mixture composition

All Gel Play Paint products contain the following chemicals:

3. Composition

  

Component

2-Hydroxyethyl Methacrylate (HEMA) CAS No. 868-77-9
EINECS No. 212-782-2 Hydroxypropyl Methacrylate

CAS No. 27813-02-1
EINECS No. 248-666-3
Silica
CAS No. 7631-86-9
EINECS No. 231-545-4
Trimethylbenzoyl Diphenylphosphine Oxide CAS No. 75980-60-8

EINECS No. 278-355-8

Paint Purple contains

Component

Bisaminomethylnorborane copolymer CAS No 146277-66-9
EINECS No Not established

Paint Flame Red contains

Component

Formaldehyde/Melamine/Tosylamine

% (w/w)

13 – 15 13 – 15 2 - 3 1.5 - 2

% (w/w)

6 - 7

% (w/w)

7 - 8

GHS Classification

Skin Irritant, Category 2, H315
Skin Sensitizer, Category 1, H317
Eye Irritant, Category 2A, H319
Skin Sensitizer, Category 1, H317
Eye Irritant, Category 2A, H319
Germ Cell Mutagenicity, Category 1B, H340 None assigned for silica bound into product. As dust:
STOT-RE, Category 1, H372
Reproductive Hazard, Category 2, H361 Chronic Aquatic Toxicity, Category 3, H412

Di-Hema Trimethylhexyl Dicarbamate CAS No. Not reported
EINECS No. Not reported

57 - 63

Skin Irritant, Category 2, H315 Skin Sensitizer, Category 1, H317 Eye Irritant, Category 2A, H319 STOT-SE, Category 3, H335

       

4- Methoxyphenol (p- Hydroxyanisole) CAS No. 150-76-5
EINECS No. 205-769-8

~0.007

Acute Toxicity, Oral, Category 4, H302
Eye Irritant, Category 2A, H319
Acute Aquatic Toxicity, Category 3, H402 Chronic Aquatic Toxicity, Category 3, H412

    

None assigned

Not known

GHS Classification

GHS Classification

Aluminum Hydroxide CAS No 21645-51-2 EINECS No 244-492-7

~0.065

None assigned

       

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UV/LED Gel Play Paint

  

Copolymer
CAS No. Proprietary EINECS No. Not known

All Paint Play Gel products except for Red, Prussian Blue, Orange and Brown contain

Component % (w/w) GHS Classification

Titanium Dioxide CI77891 0.9 - 11 Carcinogen, Category 2, H351 CAS No. 13463-67-7
EINECS No. 236-675-5

The following is a list of colorants used in Gel Play Paint products;

         

Ingredient

Iron Oxide Cl77491
Iron Oxide Cl77492
Iron Oxide Cl77499
Ferric Ferrocyanide Cl77510 Yellow 10 Lake Cl47005 Yellow 5 Lake Cl19140 Violet 2 Cl60725

Red 7 Lake Cl1585 Ext Violet Cl60730 Ultramarines Cl77007 Red 6 Cl15850

Blue 1 Lake Cl42090
Basic Violet 11:1
Basic Red 1:1
Solvent Yellow 172
Chromium Oxide Green Cl77288 Red 25 Lake Cl45410

CAS No

1309-37-1 51274-00-1 12227-89-3 14038-43-8 68814-04-0 12225-21-7 81-48-1 5281-04-9 4430-18-6 57455-37-5 5858-81-1 15792-67-3 73398-89-7 3068-39-1 68427-35-0 1308-38-9 18472-87-2

Concentration Range (wt %)

0.103 – 2.039 0.046 – 0.319 0.08 – 5.66 1.508

0.364 – 2.119 1.215 – 2.201 0.134
0.116 – 1.961 0.065

3.392
1.961
0.78 – 2.85 0.064
0.058
0.031
0.078
0.13 – 0.733

  

4. First Aid Measures

  1. 4.1  Description of First Aid Measures

    General advice: Consult a physician. Show this safety data sheet to the physician in attendance. Move away from dangerous area. Remove contaminated clothing. Completely decontaminate clothing, shoes and leather goods before re-use or discard.

    In case of eye contact: Immediately flush the contaminated eye(s) with lukewarm, gently flowing water for 20 to 30 minutes or until the chemical is removed, while holding the eyelid(s) open. Obtain medical attention immediately or transport to a medical facility and continue to flush the eyes en route.

    In case of skin contact: Wash gently and thoroughly with water and non-abrasive soap for at least 20 minutes or until chemical is removed. If signs of sensitization or irritation occur, obtain medical advice.

    If inhalation: Remove source of contamination or move victim to fresh air. If breathing is difficult , give artificial respiration. If breathing is difficult oxygen may be beneficial if administered by trained personnel, preferably on a doctor's advice. DO NOT allow the victim to move about unnecessarily. Consult a physician.

    If ingestion: Ingestion unlikely. Never give anything by mouth if victim is rapidly losing consciousness. Have victim rinse mouth thoroughly with water. Do not induce vomiting. Dilute contents of stomach with 240 to 300 ml of water. If vomiting occurs naturally have victim lean forward to reduce risk of aspiration. Seek immediate medical attention.

  2. 4.2  Most important symptoms and effects, both acute and delayed

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UV/LED Gel Play Paint

Effects of Short-Term (Acute) Exposure:

Inhalation: Due to the low volatility of this product, no significant adverse health conditions are expected to occur during the proper use of this product. In rare cases some respiratory irritation may occur.

Skin Contact: It is expected that absorption through the skin will contribute to overall exposure. Contact with skin may cause an immediate allergic reaction in persons who may be sensitized by previous exposures. Symptoms may include an immediate rash, local redness, or itching of the skin.

Eye Contact: This product is an eye irritant. Exposure to the eye may cause symptoms which include a burning sensation, tearing, redness and swelling.

Ingestion: No adverse health effects are expected if a small amount of this product is accidentally ingested.

Effects of Long-Term (Chronic) Exposure: This product contains ingredients which have been known to cause skin sensitization in some people. Sensitization may occur after prolonged or repeated exposures to this product. Prolonged contact with skin may defat tissue causing dermititis or aggravate existing skin problems.

Medical Conditions Aggravated By Exposure: Persons susceptable to skin problems may find that the use of this product will cause increased symptoms of existing skin problems.

4.3 Indication of any immediate medical attention and special treatment needed

In the event of an allergic reaction, immediate medical help is required. Allergic reactions may result in various health effects including respiration.

5. Fire Fighting Measures

  1. 5.1  Extinguishing Media
    Suitable extinguishing media: Dry chemical, carbon dioxide, water spray, foam, or water fog.

  2. 5.2  Special hazards arising from mixture: Carbon dioxide, carbon monoxide, oxides of nitrogen, undetermined organic compounds in acrid smoke.

  3. 5.3  Advice for firefighters: Do not enter fire area without proper protection. Fight fire from a safe distance, upwind. Use of water may be ineffective due to low solubility. If water is used, direct fine spray or fog at fire to cool and extinguish flames.

  4. 5.4  Further Information:
    Sensitivity to Impact: No

    Sensitivity to Static Discharge: No

    NATIONAL FIRE PROTECTION ASSOCIATION (NFPA) HAZARD INDEX:

    HEALTH: 3 FLAMMABILITY: 1 REACTIVITY: 0

    6. Accidental Release Measures

6.1 Personal precautions, protective equipment and emergency procedures

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UV/LED Gel Play Paint

Respiratory Protection: Vapours will be generated particularly if product is atomized, or heated. If used or sprayed in an enclosed area, at a minimum use a NIOSH approved organic vapour respirator. When cartridge type respirators are used, ensure that the cartridges are changedfrequently according to the manufacturer’s recommendations. Respirator selection must be done by a qualified person and be based upon a risk assessment of the work activities and exposure levels. Respirators must be fit tested and users must be clean shaven where the respirator seals to face. Exposure must be kept at or below the applicable exposure limits and the maximum use concentration of the respirator must not be exceeded.

Skin protection: Depending upon the conditions of use, protective gloves and clothing to prevent skin contact.

Eye and Face Protection: Chemical splash goggles and/or face shield must be worn when a possibility exists for eye contact due to spashing or spraying liquid. Contact lenses should not be worn.

Footwear: No specific recommendation.
Other: Emergency eyes wash fountains should be available in vicinity of use. At minimum, an eye

lavage kit should be kept on hand.

  1. 6.2  Environmental precautions

    Ensure that any release of this material is contained to prevent leakage into waterways and sanitary sewers.

  2. 6.3  Methods and materials for containment and cleanup
    Remedial Measures: Wash spill area with strong detergent and water solution, rinse with minimal

    water, if possible.

    Large Spills: For large spills, dike area and prevent leakage into waterways or sanitary sewers. Recover using spark proof equipment and store in approved vented containers for re-use or disposal.

    Small Spills: Small spills may be absorbed on an inert medium such as vermiculite or clay, then sweep into vented disposal containers.

  3. 6.4  Referencetoothersections

    For disposal, see section 13

    7. Handling and Storage

  1. 7.1  Precautions for safe handling
    Handling Procedures: Wear proper protective equipment when handling this material. Only use

    non-sparking tools when handling this material.

  2. 7.2  Conditions for safe storage, including incompatibilities

    Storage: Store indoors in a well ventilated area where the storage temperature can be maintained between 1oC and 38oC. Storage above 38oC will result in reduced product life. Store in tightly closed containers away from heat, sparks, open flame, strong oxidizers, radiation and other initiators. Prevent contamination with foreign materials, including moisture.

  3. 7.3  Specific end use(s)

    No other uses except those mentioned in Section 1.2

    8. Exposure Controls, Personal Protection

8.1 Control parameters
Components with workplace control parameters

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UV/LED Gel Play Paint

Hydroxypropyl Methacrylate, component 2-Methylpropenic Acid, (CAS No. 79-41-4) ACGIH TLV TWA: 20 ppm, eye and skin irritation,

component Methyloxirane, (CAS No. 75-56-9) ACGIH TLV-TWA: 2 ppm

4-Methoxyphenol, (CAS No 150-76-5), ACGIH TLV TWA : 5 mg/m3, eye irritation, skin damage Black (CI 77266)

Note: Silica, Calcium, aluminum borosilicate,and titanium dioxide have respiratory exposure controls, but since these components are bound into the product and are not capable of becoming airborne, exposure controls need not be listed.

8.2 Exposure controls

Engineering Controls: When using indoors, ensure adequate ventilation by using local exhaust. Mechanical ventilation is recommended for all indoor situations to control fugitive emissions. Electrical and mechanical equipment should be explosion proof.

Respiratory Protection: Vapours will be generated particularly if product is atomized, or heated. If used or sprayed in an enclosed area, at a minimum use a NIOSH approved organic vapour respirator. When cartridge type respirators are used, ensure that the cartridges are changedfrequently according to the manufacturer’s recommendations. Respirator selection must be done by a qualified person and be based upon a risk assessment of the work activities and exposure levels. Respirators must be fit tested and users must be clean shaven where the respirator seals to face. Exposure must be kept at or below the applicable exposure limits and the maximum use concentration of the respirator must not be exceeded.

Skin protection: Depending upon the conditions of use, protective gloves and clothing to prevent skin contact.

Eye and Face Protection: Chemical splash goggles and/or face shield must be worn when a possibility exists for eye contact due to spashing or spraying liquid. Contact lenses should not be worn.

Footwear: No specific recommendation.
Other: Emergency eyes wash fountains should be available in vicinity of use. Control of environmental exposure
Prevent further leakage or spillage, if safe to do so. Do not let product enter drains.

9. Physical and Chemical Properties

9.1 Information on basic physical and chemical properties Appearance: Viscous liquid, various colours

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10.1 10.2 10.3

10.4 10.5 10.6

UV/LED Gel Play Paint

Odour:
Odour Threshold:
pH:
Melting Point/Freezing Point: Initial Boiling Point:
Flash Point:
Evaporation Rate: Flammability:
Upper Explosion Limit: Lower Explosion Limit: Vapour Pressure:
Vapour Density:
Relative Density:
Solubility:
Partition Coefficient: Autoignition Temperature: Decomposition Temperature: Viscosity:
Explosive Properties: Oxidizing Properties:

Characteristic acrylic odour Not available
Not applicable
0°C

131 oC >96.7 oC

Negligible
Not flammable
No data
No data
< 0.01 @ 20oC
No data
1.15 @ 25oC (water=1)
Negligible in water
Not available
No data
No data
No data
Not explosive. Not expected to be sensitive to electrostatic discharge. No data

9.2

Other safety information: None
10. Stability and Reactivity

Reactivity

Product may become reactive if inhibitor is depleted.

Chemical Stability

Stable as supplied.

Possibility of hazardous reactions

High temperatures, inhibitor depletion, accidental impurities, or exposure to radiation or oxidizers may initiate spontaneous polymerization, generating heat and pressure. Closed containers may rupture during hazardous polymerization.

Conditions to avoid

Exposure to heat, light and moisture.

Incompatible materials

Keep away from strong oxidizers and moisture.

Hazardous decomposition products

Carbon monoxide, carbon dioxide and various oxides of nitrogen.

11.1

11. Toxicological Information

Information on toxicological effects

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UV/LED Gel Play Paint

Note to reader: We do NOT test our products on animals. In compliance with current SDS preparation requirements, the values listed are published values for generic ingredients with known animal toxicity.

Acute toxicity Component

Di-Hema Trimethylhexyl Dicarbamate, (CAS No. Proprietory) (EINECS No. None)
2-Hydroxyethyl Methacrylate (HEMA), (CAS No. 868-77-9)
( EINECS No. 212-782-2)

Hydroxypropyl Methacrylate, (CAS No. 27813-02-1)
(EINECS No. 248-666-3)
Trimethylbenzoyl Diphenylphosphine Oxide, (CAS No. 75980-60-8) (EINECS No. 278-355-8)

4- Methoxyphenol (p- Hydroxyanisole), (CAS No. 150-76-5) (EINECS No. 205-769-8)
Bisaminomethylnorborane copolymer
CAS No 146277-66-9

Aluminum Hydroxide
CAS No 21645-51-2
Iron Oxide, CAS No. 1309-37-1 EINECS No. 215-168-2
Titanium Dioxide, CAS No. 13463-67-7 EINECS No. 236-675-5
Silica, CAS No. 7631-86-9
EINECS No. 231-545-4
Iron Oxide, CAS No. 1309-37-1 EINECS No. 215-168-2

LD50

>5000 mg/kg (oral/rat)

5564 mg/kg (oral/rat)
>3000 mg/kg (dermal/rabbit)

11,200 mg/kg (oral/rat)

>5000 mg/kg (oral/rat) >2000 mg/kg (dermal/rabbit)

N/av

N/av

>2000 mg/kg (oral/female rat)

>10,000 mg/kg(oral/rat)

>25,000 mg/kg (oral/rat) >10,000 mg/mg (dermal/rabbit) 3160 mg/kg (oral/rat)

>10,000 mg/kg (oral/rat)

LC50

N/av N/av N/av N/av

N/av
N/av
N/av
N/av
>6820 mg/m3 N/av

N/av

                              

ABBREVIATION KEY: N/p: not published, N/d: not determined, N/ap: not applicable, N/av: not available Skin corrosion/irritation

Components of this mixture may cause skin irritation, H315, Category 2, Warning

Serious eye damage/eye irritation

Components of this mixture may cause eye irritation, H319, Category 2A, Warning

Respiratory or skin sensitization

Components of this mixture may cause skin sensitization, H317, Category 1, Warning

Germ Cell Mutagenicity

Components in this mixture suspected of causing genetic defects, H341, Category 2, Warning

Carcinogenicity

Not classifiable as a human carcinogen. Titanium dioxide is present in the formulation but is not in a respirable form and cannot become airborne.

Reproductive toxicity

Components in this mixture are suspected of damaging fertility or the unborn child, H361, Category 2, Warning

Specific Target Organ Toxicity – Single exposure

Components of this mixture may cause respiratory irritation, H335, Category 3, Warning

Specific Target Organ Toxicity – Repeated exposure

No information available

Aspiration Hazard

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UV/LED Gel Play Paint

12.2

12.3 12.4 12.5 12.6

Dicarbamate
2-Hydroxyethyl methacrylate Hydroxypropyl methacrylate 4-Methoxyphenol Trimethylbenzoyl

diphenylphosphine oxide

To algae:

Di-Hema Trimethylhexyl

Dicarbamate
2-Hydroxyethyl methacrylate Hydroxypropyl methacrylate 4-Methoxyphenol Trimethylbenzoyl

diphenylphosphine oxide

To daphnia:

Di-Hema Trimethylhexyl

Dicarbamate
2-Hydroxyethyl methacrylate Hydroxypropyl methacrylate 4-Methoxyphenol Trimethylbenzoyl

diphenylphosphine oxide

Persistence and degradability

No information available

Additional information

None

Toxicity To fish:

12.

Ecological Information

No data available

flow through test Fathead Minnow 227mg/l – 96 hour No data available
LC50: rainbow trout – 28.5 mg/l – 96 hour
10 – 100 mg/l

No data available

345 mg/L/72hr (Green algae) > 97 mg/L/72hr (Green algae) No data available
10 – 100 mg/l72 hr

No data available

380 mg/l
>140 mg/l
No data available 10 – 100 mg/l

12.1

Di-Hema Trimethylhexyl

2-Hydroxyethyl methacrylate (HEMA) and Hydroxypropyl methacrylate (HPMA) are considered to be readily biodegradable.
Trimethylbenzoyl diphenylphosphine oxide is considered to be poorly biodegradable.

Isobornyl acrylate. Isobornyl acrylate is not considered to be readily biodegradable.

Bioaccumulative potential

No data available

Mobility in soil

No data available

Results of PBT and vPvB assessment

Not conducted

Other adverse effects

No data available

13.

Disposal Considerations

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UV/LED Gel Play Paint

13.1 Waste treatment methods Product:

Review federal, provincial or state, and local government requirements prior to disposal. Store material for disposal as indicated in Storage Conditions. Disposal by controlled incineration or by secure land fill may be acceptable.

Contaminated packaging

Dispose as above.

14. Transport Information

All Gel Play Paint products:
Transport of Dangerous Goods (TDG and CLR): Not regulated

United States Department of Transport (49CFR): Not regulated International Air Transport Association (IATA): Not regulated International Maritime Organization (IMO): Not regulated

15. Regulatory Information

CANADIAN FEDERAL REGULATIONS:
CEPA, DOMESTIC SUBSTANCES LIST: Listed

UNITED STATES – FEDERAL REGULATIONS:
TOXIC SUBSTANCES CONTROL ACT (TSCA): All components are listed in the inventory.

CALIFORNIA Proposition 65, Safe Drinking Water and Toxicity Enforcement Act, 1986:

Methyloxirane, component CAS No 75-56-9 of Hydroxypropyl Methacrylate

OSHA, 29 CFR 1910, Subpart Z: Meets criteria for a hazardous substance.

CERCLA, 40 CFR 302: No ingredient listed

SARA 302, 40 CFR 355: Methyloxirane, component CAS No 75-56-9, Rev Date: 2008-11-03

SARA 313, 40 CFR 372: Methyloxirane, component CAS No 75-56-9, Rev Date: 2008-11-03

SARA 311/312, 40 CFR 370: Immediate (Acute) Health, Delayed (Chronic) Health

Massachusetts Right to Know: 4- Methoxyphenol (p- Hydroxyanisole), Methyloxirane,

New Jersey Right to Know: 4- Methoxyphenol (p- Hydroxyanisole), Methyloxirane, Trimethylbenzoyl Diphenylphosphine Oxide

Pennsylvania Right to Know: 4- Methoxyphenol (p- Hydroxyanisole), Methyloxirane, Trimethylbenzoyl Diphenylphosphine Oxide

16. Other Information

Original Preparation Date: August 17, 2017
Prepared by: KJ Pearson, West Vancouver, BC, V7W 1P3

 

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UV/LED Gel Play Paint

Disclaimer: This Safety Data Sheet (SDS) was prepared using information provided by CCINFO, ingredient supplier SDS and other relevant sources. This product has been classified using weight of evidence, expert judgment and previous testing as per Part 1.3 of the Fifth Edition of The Globally Harmonized System of Classification and Labelling of Chemicals (GHS). The information in this SDS is offered for your consideration and guidance when exposed to this product. Haigh Industries Inc. expressly disclaims all expressed or implied warranties and assumes no responsibilities for the accuracy or completeness of the data contained herein. The data in this SDS does not apply to use with any other product or in any other process.

This Safety Data Sheet may not be changed, or altered in any way without the expressed knowledge and permission of Haigh Industries Inc.

Revisions: None

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UV/LED Options Colours

 

SAFETY DATA SHEET

This Safety Data Sheet complies with the Canadian Hazardous Products Regulations, the United States Occupational Safety and Health

Administration (OSHA) Hazard Communication Standard, 29 CFR 1910 (OSHA HCS), and the European Union Directives.

1. Product and Supplier Identification

1.1 Product: UV/LED Options Colours

  1. 1.2  Product Use:

  2. 1.3  Producer:

    Supplier:

  3. 1.4  Emergencies (24-hour number): +1(604) 278-5851

    2. Hazards Identification

2.1 Classification of product or mixture

Note to reader: This product in an untested mixture and GHS classification is based on the classification of the ingredients and their concentrations. Proprietary ingredients do NOT exhibit any health effects not listed in this SDS.

Nail Gel

Haigh Industries Inc.,
#5 – 8118 North Fraser Way, Burnaby, B.C.
Canada, V5J 0E5

Telephone: (604) 278-5851

As above

GHS Classification:

Skin Irritation: Category 2
Eye Irritation: Category 2A
Skin Sensitization: Category 1
Specific Target Organ Toxicity, SE, Respiratory Category 3 Germ Cell Mutagenicity: Category 2
Reproductive Toxicity: Category 2

2.2 GHS Label Elements, including precautionary statements Pictogram:

 

Signal Word: Warning GHS Hazard Statements:

H315: Causes skin irritation.
H317: May cause an allergic skin reaction.
H319: Causes serious eye irritation.
H335: May cause respiratory irritation.
H341: Suspected of causing genetic defects.
H361: Suspected of damaging fertility or the unborn child

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UV/LED Options Colours

GHS Precautionary Statements:

Prevention:

Response:

P201: Obtain special instructions before use.
P202: Do not handle until all safety precautions have been read and

understood.
P261: Avoid breathing mist, vapours or spray
P264: Wash skin thoroughly after handling.
P271: Use only outdoors or in a well-ventilated area.
P272: Contaminated work clothing should not be allowed out of

the workplace.
P280: Wear protective gloves/protective clothing/eye

protection/face protection.

P302+P352: IF ON SKIN: Wash with plenty of soap and water. P304+P340: IF INHALED: Remove person to fresh air and keep

comfortable for breathing.
P305+P351+P338: IF IN EYES: Rinse cautiously with water for

several minutes. Remove contact lenses, if present and

easy to do. Continue rinsing.
P308+P313: IF exposed or concerned: Get medical advice/attention. P312: Call a POISON CENTER/doctor...if you feel unwell.
P321: Specific treatment (see Section 4).
P332+ P313: If skin irritation occurs: Get medical advice/attention. P333+P313: If skin irritation or rash occurs, get medical advice/attention P337+P313: If skin irritation or rash occurs: Get medical

advice/attention.
P362 + P364: Take off contaminated clothing and wash it before reuse.

P403+P233: Store in a well-ventilated place. Keep container tightly closed.

P405: Store locked up.

P501: Dispose of contents/container to an approved waste disposal plant.

Storage:

Disposal:

  1. 2.3  Hazards not otherwise classified (HNOC) or not covered by GHS: None

  2. 2.4  Additional Information

    Primary Routes of Entry:

    Skin Contact: Yes Skin Absorption: Yes Eye Contact: Yes Ingestion: No Inhalation: Yes

    Emergency Overview: This product contains ingredients which may cause mild eye and skin irritation in some people. For eye contact, symptoms may include a moderate burning sensation, tearing, redness, or swelling. Contact with skin may cause an allergic reaction due to prior sensitization. Local redness, rash, or itchy skin may occur in those persons with a pre-existing sensitivity or those predisposed to skin problems. In rare cases an allergic skin reaction may occur after long term contact with this product.

    Effects of Short-Term (Acute) Exposure:

    Inhalation: Due to the low volatility of this product, no significant adverse health conditions are expected to occur during the proper use of this product. In rare cases some respiratory irritation may occur.

    Skin Contact: It is expected that absorption through the skin will contribute to overall exposure. Contact with skin may cause an immediate allergic reaction in persons who may be sensitized by previous exposures. Symptoms may include an immediate rash, local redness, or itching of the skin.

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Eye Contact: This product is an eye irritant. Exposure to the eye may cause symptoms which include a burning sensation, tearing, redness and swelling.

Ingestion: No adverse health effects are expected if a small amount of this product is accidentally ingested.

Effects of Long-Term (Chronic) Exposure: This product contains ingredients which have been known to cause skin sensitization in some people. Sensitization may occur after prolonged or repeated exposures to this product. Prolonged contact with skin may defat tissue causing dermititis or aggravate existing skin problems.

Medical Conditions Aggravated By Exposure: Persons susceptable to skin problems may find that the use of this product will cause increased symptoms of existing skin problems.

3.1 Mixture composition
All Options Colours products contain the following

chemicals:

3. Composition

  

Component

2-Hydroxyethyl Methacrylate (HEMA) CAS No. 868-77-9
EINECS No. 212-782-2

Hydroxypropyl Methacrylate CAS No. 27813-02-1 EINECS No. 248-666-3

Hydroxycyclohexyl Phenyl Ketone CAS No. 947-19-3
EINECS No. 213-426-9

Trimethylbenzoyl Diphenylphosphine Oxide CAS No. 75980-60-8
EINECS No. 278-355-8

Silica Silylate
CAS No 68909-20-6 EINECS No. Not determined

% (w/w)

10 - 18

9 - 18

1.0 – 2.0

0.9 – 1.5

0.1 – 0.2

GHS Classification

Di-Hema Trimethylhexyl Dicarbamate CAS No. Not reported
EINECS No. Not reported

45 - 68

Skin Irritant, Category 2, H315 Skin Sensitizer, Category 1, H317 Eye Irritant, Category 2A, H319 STOT-SE, Category 3, H335

Skin Irritant, Category 2, H315 Skin Sensitizer, Category 1, H317 Eye Irritant, Category 2A, H319

Skin Sensitizer, Category 1, H317
Eye Irritant, Category 2A, H319
Germ Cell Mutagenicity, Category 1B, H340

No GHS Classification

Reproductive Hazard, Category 2, H361 Chronic Aquatic Toxicity, Category 3, H412

GHS Classification not determined

         

4- Methoxyphenol (p- Hydroxyanisole) CAS No. 150-76-5
EINECS No. 205-769-8

< 0.01

Acute Toxicity, Oral, Category 4, H302
Eye Irritant, Category 2A, H319
Acute Aquatic Toxicity, Category 3, H402 Chronic Aquatic Toxicity, Category 3, H412

Options Aurora Apricot, Aurora Onyx, Blue, Emerald, Gold, Maroon, Pearl, Pewter, Pink, Purple, Silver, Sparkles: Caribbean Teal, Golden Twilight, Midnight Dust, Ravishing Red, Silver Twinkle, Tangelo and Sunlite Snow also contain:

  

Component

Polyethylene Terephthalate CAS No. 25038-59-9 EINECS No. Not determined

% (w/w)

4.0 - 25

GHS Classification

No GHS Classification

     

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UV/LED Options Colours

Options Apricot Delight, Aquamarine Dream, Art Blue, Art Charcoal, Art Clear Blue, Art Clear Yellow, Art Creamy Green, Art Creamy Purple, Art Green, Art Navy Blue, Art White, Art Yellow, Bare, Bashful Pink, Berry Elegance, Berry Truffle, Blissful Pink, Blue Orbit, Blue Moon, Blue Eclipse, Bluebelle, Blush a Bit, Bronze Mist, Bursting Yellow, Buttercup, Cashmere Red, Celestial Orchid, Chai, Champagne, Charming Pink, Chiffon, Chocolat, Classic Red, Cobalt Blue, Coral Essence, Coral Pink, Coral Rose, Crazy Daisy, Cream Mint, Creamy Dream, Creamy Nude, Desert Rose, Dream Pink, Dusty Rose, Eternal Blush, Evening Grey, Fiesta Yellow, Fire, Flamingo, Floral White, Frappe Mocha, French Blue, Glacier Blue, Glamour Pink, Glass White, Goldenrod Yellow, Green Splash Hazy Khaki, Heritage Rouge, Hibiscus Pink, Honey Almond, Hypnotic Coral, Ice Apricot, Ice Blue, Ice Charcoal, Ice Coral, Ice Gold, Ice Latte, Ice Lime, Ice Marine Blue, Ice Pewter, Ice Pink, Ice Silk, Ice Turquoise, Ice Violet, Ice White, Imperial Red, Ivory Kisses, Ivory Silk, Just Peachy, Lacy Grey, Latte, Lavender Cream, Lavender Pink, Lilac Flourish, Lily Lavender, Lingerie Pink, Luminous Blossom, Lunar Grey, Majestic Violet, Maple Sugar, Mauvella, Mellow Yellow, Merlot, Mint Green, Misty Rose, Moody Sunset, Mystic Mauve, Ocean Pearl, Pageant Pink. Peach Whisper, Peachy Keen, Pink Blush, Pink Chintz, Pink Innocence, Pink Pearl, Pink Poppy, Powder Pink, Pretty in Pink, Pristine Bluff, Purple Dusk, Purple Lotus, Purple Smoke, Risky Pink, Rose Bisque, Rosette, Rosy Tan, Royal Onyx, Salmom Pink, Seafoam Green, Shadow Grey, Sheer Mikan, Sienna Sunrise, Simply Pink, Smokey Taupe, Snazzy Blue, Soft Coral, Strawberry Cream, Sun Dance, Sweet Mandarin, Sweet Maple, Teacup Rose, Teal Drop, Tender Leaf, Tender Pink, Pickled Pink, Tropical Sand, Truly Blue, Tuscan Sunset, Vintage Bluff, Violet Hue, Wild Rose and Windswept Tan

Sparkles: Blue, Bronze, Caribbean Teal, Clear, Gold, Golden Twilight, Lilac, Pink, Raspberry, Sunlite Snow also contain:

  

Component

Titanium Dioxide CI77891 CAS No. 13463-67-7 EINECS No. 236-675-5

Options Matte On also contains: Component

Polypropylene
CAS No. 9003-07-0 EINECS No. Not determined

% (w/w)

0.2 – 6.0

% (w/w)

8 – 10.0

GHS Classification

Carcinogen, Category 2, H351

GHS Classification

No GHS Classification

           

Options Blue Eclipse, Celestial Orchid, Lunar Grey, Merlot, Sienna Sunrise, Tuscan Sunset
Sparkles: Blue, Bronze, Caribbean Teal, Clear, Gold, Golden Twilight, Lilac, Midnight Dusk, Pink, Raspberry, Ravishing Red, Star Dust, Sunlite Snow also contain:

  

Component

Calcium Sodium Borosilicate CAS No. 65997-17-3 EINECS No. Not determined

Options Sparkles Tangelo also contains: Component

Calcium Aluminum Borosilicate CAS No. 65997-17-3
EINECS No. 266-046-0

% (w/w)

0.2 – 1.5

% (w/w)

1.0 - 1.5

GHS Classification

Carcinogen, Category 2, H351

GHS Classification

Carcinogenicity, Category 2, H351

           

Options Blue Eclipse, Blush a Bit, Bronze Mist, Bursting Yellow, Cashmere Red, Celestial Orchid, Chai, Champagne, Chiffon, Desert Rose, Dream Pink, Flamingo, Frappe Mocha, Ice Apricot, Ice Blue, Ice Charcoal, Ice Coral, Ice Gold, Ice Latte, Ice Lime, Ice Marine Blue, Ice Pewter, Ice Pink, Ice Silk, Ice Turquoise, Ice Violet, Ice White, Lunar Grey, Mauvella, Mystic Mauve, Ocean Pearl, Peachy Keen, Pink Pearl, Risky Pink, Satin Pearl, Sienna Sunrise, Simply Pink, Snazzy Blue, Soft Coral, Tropical Sand and Tuscan Sunset,

Sparkles: Bronze, Gold, Golden Twilight, Silver Twinkle also contain:

  

Component

Mica CI77019
CAS No. 12001-26-2 EINECS No. 310-127-6

% (w/w)

0.09 - 9

GHS Classification

No GHS Classification

     

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UV/LED Options Colours

Options Majestic Violet, Purple Lotus, and Tickled Pink also contain:
Component % (w/w) GHS Classification

Options Blue Moon, Hypnotic Coral, Lime Twist, Pink Flirt, Sizzling Pink, and Yellow Flare also contain: Component % (w/w) GHS Classification

Options Ice Apricot, Ice Blue, Ice Charcoal, Ice Coral, Ice Gold, Ice Latte, Ice Lime, Ice Marine Blue, Ice Pewter, Ice Pink, Ice Silk, Ice Turquoise, Ice Violet, Ice White also contain:

Component % (w/w) GHS Classification

Synthetic Fluorphlogopite 4 - 5 No GHS Classification CAS No. 12003-38-2
EINECS No. Not determined

Options Art Black, Art Charcoal, Art Navy Blue Aurora Apricot, Aurora Emerald, Aurora Maroon, Aurora Pink, Bare, Bashful Pink, Berry Elegance, Berry Truffle, Blue Moon, Blue Eclipse, Cashmere Red, Celestial Orchid, Chai, Chocolat, Crazy Daisy, Cream Mint, Creamy Dream, Creamy Nude, Divine Cocoa, Eternal Blush, Evening Grey, Frappe Mocha, French Blue, Glass Black, Goldenrod Yellow, Hazy Khaki, Heritage Rouge, Honey Almond, Ice Charcoal, Ice Gold, Ice Pewter, Ivory Kisses, Ivory Silk, Just Peachy, Lacy Grey, Latte, Lilac Flourish, London Fog, Luminous Blossom, Lunar Grey, Maple Sugar, Mellow Yellow, Merlot, Misty Rose, Moody Sunset, Mulberry, Mystic Mauve, Ocean Pearl, Pageant Pink, Purple Dusk, Purple Smoke, Rich Expresso, Rose Bisque, Rosette, Rosy Tan, Royal Onyx, Shadow Grey, Sparkles Midnight Dusk, Sparkles Raspberry, Strawberry Cream, Sweet Maple, Teacup Rose, Tender Leaf, Truly Blue and Windswept Tan also contain:

  

Bis(glycidoxyphenyl)propane/ Bisaminomethylnorbornana copolymer CAS No. 146277-66-9
EINECS No. Not known

3.5 – 7.0

GHS Classification not determined (unknown)

  

Formaldehyde/Melamine/Tosylamine Copolymer
CAS No. Mixture
EINECS No. Not determined

4-5

No GHS Classification

         

Component

Iron Oxide
CAS No. 12227-89-3 EINECS No. 235-442-5

% (w/w) GHS Classification

Trace – No GHS Classification 4.0

    

Options Blue Eclipse, Bursting Yellow, Celestial Orchid, Champagne, Chiffon, Fire, Ice Apricot, Ice Gold, Ice Silk, Lunar Grey, Merlot, Moody Sunset, Ocean pearl, Peachy Keen, Risky Pink, Sienna Sunrise, Snazzy Blue, and Tuscan Sunset
Sparkles: Caribbean Teal, Blue Bronze, Clear, Gold, Golden Twilight, Lilac, Midnight Dust, Pink, Raspberry, Ravishing Red, Star Dust, and Sunlite Snow, Tangelo

  

Component

Silica
CAS No. 7631-86-9 EINECS No. 231-545-4

% (w/w)

Trace – 3.0

GHS Classification

None assigned for silica bound into product. As dust:
STOT-RE, Category 1, H372

     

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UV/LED Options Colours

Options Bare, Bashful Pink, Berry Truffle, Blush a Bit, Bronze Mist, Chai, Champagne, Chiffon, Crazy Daisy, Cream Mint, Creamy Dream, Creamy Nude, Desert Rose, Divine Cocoa, Dream Pink, Dusty Rose, Eternal Blush, Evening Grey, Fire, Frappe Mocha, Goldenrod Yellow, Hazy Khaki, Heritage Rouge, Honey Almond, Ice Apricot, Ice Gold, Ice Latte, Ice Silk, Ivory Kisses, Ivory Silk, Just Peachy, Latte, Lavender Cream, London Fog, Luminous Blossom, Maple Sugar, Misty Rose, Mystic Mauve, Pageant Pink, Peachy Keen, Pink Blush, Powder Pink, Pristine Buff, Purple Smoke, Rose Bisque, Rosy Tan, Sienna Sunrise, Smokey Taupe, Sun Dance, Sweet Maple, Teacup Rose, Tender Leaf, Tropical Sand, Tuscan Sunset, Windswept Tan

Sparkles: Bronze, Caribbean Teal, Gold, Golden Twilight, Ravishing Red, and Tangelo also contain:

  

Component

Iron Oxide CI77491 CAS No. 1309-37-1 EINECS No. 215-168-2

% (w/w) GHS Classification

Trace – No GHS Classification 1.0

    

Options Aurora: Apricot, Blue, Emerald, Gold, Onyx, Maroon, Pearl, Pewter, Pink, Purple and Silver
Blue Eclipse, Celestial Orchid, Lunar Grey,
Sparkles: Caribbean Teal, Golden Twilight, Midnight Dust, Ravishing Red, Silver Twinkle, Sunlite Snow, and Tangelo also contain:

  

Component

Aluminum Powder Cl77000 CAS No. 7429-90-5 EINECS No. 234-072-3

% (w/w) GHS Classification

0.012 – Flammable Solids, Category 1, H228 0.25

    

Options Bare, Bashful Pink, Berry Truffle, Crazy Daisy, Cream Mint, Creamy Dream, Creamy Nude, Divine Cocoa, Eternal Blush, Evening Grey, Goldenrod Yellow, Hazy Khaki, Heritage Rouge, Honey Almond, Ice Gold, Ivory Kisses, Ivory Silk, Just Peachy, Latte, Luminous Blossom, Maple Sugar, Mystic Mauve, Pageant Pink, Rose Bisque, Smokey Taupe, Sweet Maple, Tender Leaf and Windswept Tan also contain:

  

Component

Iron Oxide CI77492 CAS No. 51274-00-1 EINECS No. 257-098-5

Options Aurora Blue also contains: Component

Polymethyl Methacrylate CAS No. 9011-14-7 EINECS No. Not determined

% (w/w)

Trace – 0.2

% (w/w)

1.0 – 1.5

GHS Classification

No GHS Classification

GHS Classification

No GHS Classification

           

Options Aurora Apricot, Aurora Blue, Aurora Emerald, Aurora Gold, Aurora Maroon, Aurora Onyx, Aurora Pearl, Aurora Pewter, Aurora Pink, Aurora Purple, Aurora Silver,
Sparkles: Caribbean Teal, Golden Twilight, Midnight Dust, Ravishing Red, Silver Twinkle, Sunlite Snow and Tangelo also contain:

  

Component

Polyurethane 11
CAS No. 68258-82-2 EINECS No. Not determined

Options Aurora Pewter also contains: Component

Acrylates Copolymer
CAS No. 25035-69-2 EINECS No. Not determined

% (w/w)

0.1 – 1.0

% (w/w)

1.0 – 1.5

GHS Classification

No GHS Classification

GHS Classification

No GHS Classification

            

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UV/LED Options Colours

Options Aurora Blue and Aurora Pearl also contain:

Component % (w/w)

Polyurethane 33 0.4 – 1.2 CAS No. 125826-44-0
EINECS No. Not determined

GHS Classification

No GHS Classification

       

Options Majestic Violet, Purple Lotus, and Tickled Pink also contain:

  

Component

Aluminum Hydroxide CAS No. 21645-51-2 EINECS No. 244-492-7

Options Lime Twist also contains: Component

Diethylaminomethylcoumarin CAS No. 91-44-1
EINECS No. 270-393-3

% (w/w)

0.1 – 0.6

% (w/w)

0.1 – 0.5

GHS Classification

No GHS Classification

GHS Classification

No GHS Classification

           

Options Blue Eclipse, Bursting Yellow, Celestial Orchid, Champagne, Chiffon, Ice Apricot, Ice Blue, Ice Charcoal, Ice Coral, Ice Gold, Ice Latte, Ice Lime, Ice Marine Blue, Ice Pewter, Ice Pink, Ice Silk, Ice Turquoise, Ice Violet, Ice White, Lunar Grey, Merlot, Moody Sunset, Ocean Pearl, Peachy Keen, Risky Pink, Siena Sunrise, Snazzy Blue, Tuscan Sunset, Sparkles: Caribbean Teal, Blue, Bronze, Clear, Gold, Golden Twilight, Lilac, Midnight Dust, Pink. Raspberry, Ravishing Red, Star Dust, Sunlite Snow, Tangelo also contain:

Component % (w/w) GHS Classification

Tin Oxide Cl77861 0.002 - .5 No GHS Classification CAS No. 18282-10-5
EINECS No. 242-159-0

Note to reader; Classification of Titanium Dioxide and Calcium Sodium Borosilicate as Category 2 carcinogens is based upon recent listing by IARC as a Group 2B carcinogen. This classification does NOT apply to use in cosmetics or nail gels when bound by other ingredients making the possibility of airborne particles impossible. Silica is classified as a STOT-RE, Specific Target Organ Toxicity-Repeated exposure, lungs, only if airborne and able to enter the lungs. When bound into this product as a mixture, this classification would not apply.

Then following is a list of colorants used in Options Colours products that are not already listed in one of the Tables;

       

Ingredient

Manganese Violet Cl77742 Red 6 CI15850 Ultramarines CI77007
Blue 1 Lake CI42090 Yellow 10 Lake CI47005 Yellow 5 Lake CI19140 Red 7 Lake CI15850

Ferric Ferrocyanide Cl77510 Basic Red
Red 28 CI45410
Chromium Oxide CI77288 Violet 2 CI60725

Carmine Cl75470
Red 30 Talc Lake CI73360 Red 33 Lake CI17200 Black 2 CI77266

CAS No

10101-66-3 5858-81-1 57455-90-5 15792-67-3 68814-04-0 12225-21-7 5281-04-9 14038-43-8 3068-39-1 18472-87-2 1308-38-9 81-48-1 1390-65-4 2379-74-0 3567-66-6 1333-86-4

Concentration Range (wt %)

0.03 – 0.5 0.04 – 1.0 Trace – 0.3 Trace – 4.0 0.02 – 1.1 Trace – 2.0 Trace – 1.2 Trace – 0.70 0.1 – 0.2 0.14 – 1.5 Trace – 0.6 0.01 – 0.1 0.02 – 0.07 0.01 – 0.40 0.01 – 1.5 ~0.02

   

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4. First Aid Measures

  1. 4.1  Description of First Aid Measures

    General advice: Consult a physician. Show this safety data sheet to the physician in attendance. Move away from dangerous area. Remove contaminated clothing. Completely decontaminate clothing, shoes and leather goods before re-use or discard.

    In case of eye contact: Immediately flush the contaminated eye(s) with lukewarm, gently flowing water for 20 to 30 minutes or until the chemical is removed, while holding the eyelid(s) open. Obtain medical attention immediately or transport to a medical facility and continue to flush the eyes en route.

    In case of skin contact: Wash gently and thoroughly with water and non-abrasive soap for at least 20 minutes or until chemical is removed. If signs of sensitization or irritation occur, obtain medical advice.

    If inhalation: Remove source of contamination or move victim to fresh air. If breathing is difficult, give artificial respiration. If breathing is difficult oxygen may be beneficial if administered by trained personnel, preferably on a doctor's advice. DO NOT allow the victim to move about unnecessarily. Consult a physician.

    If ingestion: Ingestion unlikely. Never give anything by mouth if victim is rapidly losing consciousness. Have victim rinse mouth thoroughly with water. Do not induce vomiting. Dilute contents of stomach with 240 to 300 ml of water. If vomiting occurs naturally have victim lean forward to reduce risk of aspiration. Seek immediate medical attention.

  2. 4.2  Most important symptoms and effects, both acute and delayed Effects of Short-Term (Acute) Exposure:

    Inhalation: Due to the low volatility of this product, no significant adverse health conditions are expected to occur during the proper use of this product. In rare cases some respiratory irritation may occur.

    Skin Contact: It is expected that absorption through the skin will contribute to overall exposure. Contact with skin may cause an immediate allergic reaction in persons who may be sensitized by previous exposures. Symptoms may include an immediate rash, local redness, or itching of the skin.

    Eye Contact: This product is an eye irritant. Exposure to the eye may cause symptoms which include a burning sensation, tearing, redness and swelling.
    Ingestion: No adverse health effects are expected if a small amount of this product is accidentally ingested.

    Effects of Long-Term (Chronic) Exposure: This product contains ingredients which have been known to cause skin sensitization in some people. Sensitization may occur after prolonged or repeated exposures to this product. Prolonged contact with skin may defat tissue causing dermititis or aggravate existing skin problems.

    Medical Conditions Aggravated By Exposure: Persons susceptable to skin problems may find that the use of this product will cause increased symptoms of existing skin problems.

  3. 4.3  Indication of any immediate medical attention and special treatment needed

    In the event of an allergic reaction, immediate medical help is required. Allergic reactions may result in various health effects including respiration.

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5. Fire Fighting Measures

  1. 5.1  Extinguishing Media
    Suitable extinguishing media: Dry chemical, carbon dioxide, water spray, foam, or water fog.

  2. 5.2  Special hazards arising from mixture: Carbon dioxide, carbon monoxide, oxides of nitrogen, undetermined organic compounds in acrid smoke.

  3. 5.3  Advice for firefighters: Do not enter fire area without proper protection. Fight fire from a safe distance, upwind. Use of water may be ineffective due to low solubility. If water is used, direct fine spray or fog at fire to cool and extinguish flames.

  4. 5.4  Further Information:
    Sensitivity to Impact: No

    Sensitivity to Static Discharge: No

    NATIONAL FIRE PROTECTION ASSOCIATION (NFPA) HAZARD INDEX:

    HEALTH: 3 FLAMMABILITY: 1 REACTIVITY: 0

    6. Accidental Release Measures

  1. 6.1  Personal precautions, protective equipment and emergency procedures

    Respiratory Protection: Vapours will be generated particularly if product is atomized, or heated. If used or sprayed in an enclosed area, at a minimum use a NIOSH approved organic vapour respirator. When cartridge type respirators are used, ensure that the cartridges are changed frequently according to the manufacturer’s recommendations. Respirator selection must be done by a qualified person and be based upon a risk assessment of the work activities and exposure levels. Respirators must be fit tested and users must be clean shaven where the respirator seals to face. Exposure must be kept at or below the applicable exposure limits and the maximum use concentration of the respirator must not be exceeded.

    Skin protection: Depending upon the conditions of use, protective gloves and clothing to prevent skin contact.

    Eye and Face Protection: Chemical splash goggles and/or face shield must be worn when a possibility exists for eye contact due to spashing or spraying liquid. Contact lenses should not be worn.

    Footwear: No specific recommendation.
    Other: Emergency eyes wash fountains should be available in vicinity of use. At minimum, an eye

    lavage kit should be kept on hand.

  2. 6.2  Environmental precautions

    Ensure that any release of this material is contained to prevent leakage into waterways and sanitary sewers.

  3. 6.3  Methods and materials for containment and cleanup
    Remedial Measures: Wash spill area with strong detergent and water solution, rinse with minimal

    water, if possible.

    Large Spills: For large spills, dike area and prevent leakage into waterways or sanitary sewers. Recover using spark proof equipment and store in approved vented containers for re-use or disposal.

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Small Spills: Small spills may be absorbed on an inert medium such as vermiculite or clay, then sweep into vented disposal containers.

6.4 Referencetoothersections

For disposal, see section 13

7. Handling and Storage

  1. 7.1  Precautions for safe handling
    Handling Procedures: Wear proper protective equipment when handling this material. Only use

    non-sparking tools when handling this material.

  2. 7.2  Conditions for safe storage, including incompatibilities

    Storage: Store indoors in a well-ventilated area where the storage temperature can be maintained between 1oC and 38oC. Storage above 38oC will result in reduced product life. Store in tightly closed containers away from heat, sparks, open flame, strong oxidizers, radiation and other initiators. Prevent contamination with foreign materials, including moisture.

  3. 7.3  Specific end use(s)

    No other uses except those mentioned in Section 1.2

    8. Exposure Controls, Personal Protection

  1. 8.1  Control parameters
    Components with workplace control parameters

    Hydroxypropyl Methacrylate, component 2-Methylpropenic Acid, (CAS No. 79-41-4) ACGIH TLV TWA: 20 ppm, eye and skin irritation,

    component Methyloxirane, (CAS No. 75-56-9) ACGIH TLV-TWA: 2 ppm

    4-Methoxyphenol, (CAS No 150-76-5), ACGIH TLV TWA : 5 mg/m3, eye irritation, skin damage

    Black 2 (CI 77266) CAS No1333-86-4, ACGIH TLV-TWA: 3.5 mg/m3

    Note: Silica, calcium aluminum borosilicate, calcium sodium borosilicate and titanium dioxide have respiratory exposure controls, but since these components are bound into the product and are not capable of becoming airborne, exposure controls need not be listed.

  2. 8.2  Exposure controls

    Engineering Controls: When using indoors, ensure adequate ventilation by using local exhaust. Mechanical ventilation is recommended for all indoor situations to control fugitive emissions. Electrical and mechanical equipment should be explosion proof.

    Respiratory Protection: Vapours will be generated particularly if product is atomized, or heated. If used or sprayed in an enclosed area, at a minimum use a NIOSH approved organic vapour respirator. When cartridge type respirators are used, ensure that the cartridges are changed frequently according to the manufacturer’s recommendations. Respirator selection must be done by a qualified person and be based upon a risk assessment of the work activities and exposure levels. Respirators must be fit tested and users must be clean shaven where the respirator seals to face. Exposure must be kept at or below the applicable exposure limits and the maximum use concentration of the respirator must not be exceeded.

    Skin protection: Depending upon the conditions of use, protective gloves and clothing to prevent skin contact.

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Eye and Face Protection: Chemical splash goggles and/or face shield must be worn when a possibility exists for eye contact due to spashing or spraying liquid. Contact lenses should not be worn.

Footwear: No specific recommendation.
Other: Emergency eyes wash fountains should be available in vicinity of use.

Control of environmental exposure

Prevent further leakage or spillage, if safe to do so. Do not let product enter drains.

9. Physical and Chemical Properties

9.1 Information on basic physical and chemical properties

Appearance: Odour:
Odour Threshold: pH:

Melting Point/Freezing Point: Initial Boiling Point:
Flash Point:
Evaporation Rate: Flammability:

Upper Explosion Limit: Lower Explosion Limit: Vapour Pressure: Vapour Density: Relative Density: Solubility:

Partition Coefficient: Autoignition Temperature: Decomposition Temperature: Viscosity:
Explosive Properties: Oxidizing Properties:

Viscous liquid, various colours Characteristic acrylic odour Not available
Not applicable

0°C 131 oC

>96.7 oC
Negligible
Not flammable
No data
No data
< 0.01 @ 20oC
No data
1.15 @ 25oC (water=1)
Negligible in water
Not available
No data
No data
No data
Not explosive. Not expected to be sensitive to electrostatic discharge. No data

9.2

Other safety information: None
10. Stability and Reactivity

Reactivity

Product may become reactive if inhibitor is depleted.

Chemical Stability

Stable as supplied.

Possibility of hazardous reactions

High temperatures, inhibitor depletion, accidental impurities, or exposure to radiation or oxidizers may initiate spontaneous polymerization, generating heat and pressure. Closed containers may rupture during hazardous polymerization.
Conditions to avoid
Exposure to heat, light and moisture.

Incompatible materials

Keep away from strong oxidizers and moisture.

Hazardous decomposition products

Carbon monoxide, carbon dioxide and various oxides of nitrogen.

10.1 10.2 10.3

10.4 10.5 10.6

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11. Toxicological Information

11.1 Information on toxicological effects

Note to reader: We do NOT test our products on animals. In compliance with current SDS preparation requirements, the values listed are published values for generic ingredients with known animal toxicity.

Acute toxicity
Component
Di-Hema Trimethylhexyl Dicarbamate, (CAS No. Proprietory) EINECS No. None
2-Hydroxyethyl Methacrylate (HEMA), (CAS No. 868-77-9) EINECS No. 212-782-2
Hydroxypropyl Methacrylate, (CAS No. 27813-02-1) EINECS No. 248-666-3

4- Methoxyphenol (p- Hydroxyanisole), (CAS No. 150-76-5) EINECS No. 205-769-8

Polyethylene Terephthalate CAS No. 25038-59-9

Calcium Aluminum Borosilicate, Calcium Sodium Borosilicate CAS No. 65997-17-3

Iron Oxide, CAS No. 1309-37-1 EINECS No. 215-168-2

Titanium Dioxide, CAS No. 13463-67-7 EINECS No. 236-675-5

Black (CI77266), Carbon, mesoporous, CAS No 1333-86-4 EINECS No 215-609-9

Silica, CAS No. 7631-86-9 EINECS No. 231-545-4

Iron Oxide, CAS No. 1309-37-1 EINECS No. 215-168-2

Tin Oxide, CAS No 18282-10-10 EINECS No 242-159-0

Aluminum Powder CAS No 7429-90-5 EINECS No 234-072-3

Diethylaminomethylcoumarin CAS No. 91-44-1

LD50

>5000 mg/kg (oral/rat)

5564 mg/kg (oral/rat)
>3000 mg/kg (dermal/rabbit)

11,200 mg/kg (oral/rat)

N/av

N/av

N/av

>10,000 mg/kg(oral/rat)

>25,000 mg/kg (oral/rat) >10,000 mg/mg (dermal/rabbit)

>15,400 mg/kg (oral/rat) 3160 mg/kg (oral/rat) >10,000 mg/kg (oral/rat) >20,000 mg/kg (oral/rat) N/av

5000 mg/kg (oral/rat)

LC50

N/av N/av N/av

N/av
N/av
N/av
N/av
>6820 mg/m3 6750 mg/m3 N/av

N/av N/av N/av N/av

         

Trimethylbenzoyl Diphenylphosphine Oxide, (CAS No. 75980-60-8) EINECS No. 278-355-8

>5000 mg/kg (oral/rat) >2000 mg/kg (dermal/rabbit)

N/av

                         

ABBREVIATION KEY: N/p: not published, N/d: not determined, N/ap: not applicable, N/av: not available Skin corrosion/irritation

Components of this mixture may cause skin irritation, H315, Category 2, Warning

Serious eye damage/eye irritation

Components of this mixture may cause eye irritation, H319, Category 2A, Warning

Respiratory or skin sensitization

Components of this mixture may cause skin sensitization, H317, Category 1, Warning

Germ Cell Mutagenicity

Components in this mixture suspected of causing genetic defects, H341, Category 2, Warning

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Carcinogenicity

Not classifiable as a human carcinogen. Titanium dioxide is present in the formulation but is not in a respirable form and cannot become airborne.

Reproductive toxicity

Components in this mixture are suspected of damaging fertility or the unborn child, H361, Category 2, Warning

Specific Target Organ Toxicity – Single exposure

Components of this mixture may cause respiratory irritation, H335, Category 3, Warning

Specific Target Organ Toxicity – Repeated exposure

No information available

Aspiration Hazard

No information available

Additional information

None

12.1 Toxicity To fish:

12.

Ecological Information

No data available

flow through test Fathead Minnow 227mg/l – 96 hour No data available
LC50: rainbow trout – 28.5 mg/l – 96 hour
10 – 100 mg/l

No data available

345 mg/L/72hr (Green algae) > 97 mg/L/72hr (Green algae) No data available
10 – 100 mg/l72 hr

No data available

380 mg/l
>140 mg/l
No data available 10 – 100 mg/l

Di-Hema Trimethylhexyl

Dicarbamate
2-Hydroxyethyl methacrylate Hydroxypropyl methacrylate 4-Methoxyphenol Trimethylbenzoyl

diphenylphosphine oxide

To algae:

Di-Hema Trimethylhexyl Dicarbamate
2-Hydroxyethyl methacrylate Hydroxypropyl methacrylate 4-Methoxyphenol Trimethylbenzoyl

diphenylphosphine oxide

To daphnia:

Di-Hema Trimethylhexyl

Dicarbamate
2-Hydroxyethyl methacrylate Hydroxypropyl methacrylate 4-Methoxyphenol Trimethylbenzoyl

diphenylphosphine oxide

12.2 Persistence and degradability

2-Hydroxyethyl methacrylate (HEMA) and Hydroxypropyl methacrylate (HPMA) are considered to be readily biodegradable.
Trimethylbenzoyl diphenylphosphine oxide is considered to be poorly biodegradable.
.

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12.3 12.4 12.5 12.6

13.1

Bioaccumulative potential

No data available

Mobility in soil

No data available

Results of PBT and vPvB assessment

Not conducted

Other adverse effects

No data available

13. Disposal Considerations

Waste treatment methods

Product:

Review federal, provincial or state, and local government requirements prior to disposal. Store material for disposal as indicated in Storage Conditions. Disposal by controlled incineration or by secure land fill may be acceptable.

Contaminated packaging

Dispose as above.

14. Transport Information

All Options Colours products:
Transport of Dangerous Goods (TDG and CLR): Not regulated

United States Department of Transport (49CFR): Not regulated International Air Transport Association (IATA): Not regulated International Maritime Organization (IMO): Not regulated

15. Regulatory Information

CANADIAN FEDERAL REGULATIONS:
CEPA, DOMESTIC SUBSTANCES LIST: Listed

UNITED STATES – FEDERAL REGULATIONS:
TOXIC SUBSTANCES CONTROL ACT (TSCA): All components are listed in the inventory.

CALIFORNIA Proposition 65, Safe Drinking Water and Toxicity Enforcement Act, 1986:

Methyloxirane, component CAS No 75-56-9 of Hydroxypropyl Methacrylate

OSHA, 29 CFR 1910, Subpart Z: Meets criteria for a hazardous substance.

CERCLA, 40 CFR 302: No ingredient listed

SARA 302, 40 CFR 355: Methyloxirane, component CAS No 75-56-9, Rev Date: 2008-11-03

SARA 313, 40 CFR 372: Methyloxirane, component CAS No 75-56-9, Rev Date: 2008-11-03

SARA 311/312, 40 CFR 370: Immediate (Acute) Health, Delayed (Chronic) Health

Massachusetts Right to Know: 4- Methoxyphenol (p- Hydroxyanisole), Methyloxirane,

New Jersey Right to Know: 4- Methoxyphenol (p- Hydroxyanisole), Methyloxirane, Trimethylbenzoyl Diphenylphosphine Oxide

Pennsylvania Right to Know: 4- Methoxyphenol (p- Hydroxyanisole), Methyloxirane, Trimethylbenzoyl Diphenylphosphine Oxide

 

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16. Other Information

Original Preparation Date: August 17, 2017

Prepared by: KJ Pearson, West Vancouver, BC, V7W 1P3

Disclaimer: This Safety Data Sheet (SDS) was prepared using information provided by CCINFO, ingredient supplier SDS and other relevant sources. This product has been classified using weight of evidence, expert judgment and previous testing as per Part 1.3 of the Seventh Edition of The Globally Harmonized System of Classification and Labelling of Chemicals (GHS). The information in this SDS is offered for your consideration and guidance when exposed to this product. Haigh Industries Inc. expressly disclaims all expressed or implied warranties and assumes no responsibilities for the accuracy or completeness of the data contained herein. The data in this SDS does not apply to use with any other product or in any other process.

This Safety Data Sheet may not be changed, or altered in any way without the expressed knowledge and permission of Haigh Industries Inc.

Revisions: New formulations April 23, 2018

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SAFETY DATA SHEET

This Safety Data Sheet complies with the Canadian Controlled Product Regulations, the United States Occupational Safety and Health

Administration (OSHA) Hazard Communication Standard, 29 CFR 1910 (OSHA HCS), and the European Union Directives.

1. Product and Supplier Identification

1.1 Product: UV/LED Luxio Gels

Luxio Base, Luxio Build, Luxio Colours, Luxio Gloss

  1. 1.2  Product Use:

  2. 1.3  Producer:

    Supplier:

  3. 1.4  Emergencies (24-hour number): +1(604) 278-5851

    2. Hazards Identification

2.1 Classification of product or mixture

Note to reader: This product in an untested mixture and GHS classification is based on the classification of the ingredients and their concentrations. Proprietary ingredients do NOT exhibit any health effects not listed in this SDS.

Nail Gel

Haigh Industries Inc.,
#5 – 8118 North Fraser Way, Burnaby, B.C.
Canada, V5J 0E5

Telephone: (604) 278-5851

As above

GHS Classification:

Skin Irritation: Category 2
Eye Irritation: Category 2A
Skin Sensitization: Category 1
Specific Target Organ Toxicity, SE, Respiratory Category 3 Germ Cell Mutagenicity: Category 2
Reproductive Toxicity: Category 2

2.2 GHS Label Elements, including precautionary statements Pictogram:

 

Signal Word: Warning GHS Hazard Statements:

H315: Causes skin irritation.
H317: May cause an allergic skin reaction.
H319: Causes serious eye irritation.
H335: May cause respiratory irritation.
H341: Suspected of causing genetic defects.
H361: Suspected of damaging fertility or the unborn child.

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GHS Precautionary Statements:

Prevention:

Response:

P201: Obtain special instructions before use.
P202: Do not handle until all safety precautions have been read and

understood.
P261: Avoid breathing mist, vapours or spray
P264: Wash skin thoroughly after handling.
P271: Use only outdoors or in a well-ventilated area.
P272: Contaminated work clothing should not be allowed out of

the workplace.
P280: Wear protective gloves/protective clothing/eye

protection/face protection.

P302+P352: IF ON SKIN: Wash with plenty of soap and water. P304+P340: IF INHALED: Remove person to fresh air and keep

comfortable for breathing.
P305+P351+P338: IF IN EYES: Rinse cautiously with water for

several minutes. Remove contact lenses, if present and

easy to do. Continue rinsing.
P308+P313: IF exposed or concerned: Get medical advice/attention. P312: Call a POISON CENTER/doctor...if you feel unwell.
P321: Specific treatment (see Section 4).
P332+ P313: If skin irritation occurs: Get medical advice/attention. P333+P313: If skin irritation or rash occurs, get medical advice/attention P337+P313: If skin irritation or rash occurs: Get medical

advice/attention.
P362 + P364: Take off contaminated clothing and wash it before reuse.

P403+P233: Store in a well-ventilated place. Keep container tightly closed.

P405: Store locked up.

P501: Dispose of contents/container to an approved waste disposal plant.

Storage:

Disposal:

  1. 2.3  Hazards not otherwise classified (HNOC) or not covered by GHS: None

  2. 2.4  Additional Information

    Primary Routes of Entry:

    Skin Contact: Yes Skin Absorption: Yes Eye Contact: Yes Ingestion: No Inhalation: Yes

    Emergency Overview: This product contains ingredients which may cause mild eye and skin irritation in some people. For eye contact, symptoms may include a moderate burning sensation, tearing, redness, or swelling. Contact with skin may cause an allergic reaction due to prior sensitization. Local redness, rash, or itchy skin may occur in those persons with a pre-existing sensitivity or those predisposed to skin problems. In rare cases an allergic skin reaction may occur after long term contact with this product.

    Effects of Short-Term (Acute) Exposure:

    Inhalation: Due to the low volatility of this product, no significant adverse health conditions are expected to occur during the proper use of this product. In rare cases some respiratory irritation may occur.

    Skin Contact: It is expected that absorption through the skin will contribute to overall exposure. Contact with skin may cause an immediate allergic reaction in persons who may be sensitized by previous exposures. Symptoms may include an immediate rash, local redness, or itching of the skin.

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Eye Contact: This product is an eye irritant. Exposure to the eye may cause symptoms which

include a burning sensation, tearing, redness and swelling.

Ingestion: No adverse health effects are expected if a small amount of this product is accidentally ingested.

Effects of Long-Term (Chronic) Exposure: This product contains ingredients which have been known to cause skin sensitization in some people. Sensitization may occur after prolonged or repeated exposures to this product. Prolonged contact with skin may defat tissue causing dermititis or aggravate existing skin problems.

Medical Conditions Aggravated By Exposure: Persons susceptable to skin problems may find that the use of this product will cause increased symptoms of existing skin problems.

3. Composition

3.1 Mixture composition

All Luxio Gel products contain the following chemicals:

  

Component

2-Hydroxyethyl Methacrylate (HEMA) CAS No. 868-77-9
EINECS No. 212-782-2

Hydroxypropyl Methacrylate CAS No. 27813-02-1 EINECS No. 248-666-3

Hydroxycyclohexyl Phenyl Ketone (CAS No. 947-19-3)
EINECS No 213-426-9

Trimethylbenzoyl Diphenylphosphine Oxide CAS No. 75980-60-8
EINECS No. 278-355-8

Silica Silylate
(CAS No. 68909-20-6) EINECS No. Not known

% (w/w)

10 – 20

7 – 15

1 - 3

1 - 2

0.2 – 1.0

GHS Classification

Skin Irritant, Category 2, H315 Skin Sensitizer, Category 1, H317 Eye Irritant, Category 2A, H319

Skin Sensitizer, Category 1, H317
Eye Irritant, Category 2A, H319
Germ Cell Mutagenicity, Category 1B, H340

Not classified as hazardous

Reproductive Hazard, Category 2, H361 Chronic Aquatic Toxicity, Category 3, H412

Not classified as hazardous

Di-Hema Trimethylhexyl Dicarbamate CAS No. Not reported
EINECS No. Not reported

60 - 75

Skin Irritant, Category 2, H315 Skin Sensitizer, Category 1, H317 Eye Irritant, Category 2A, H319 STOT-SE, Category 3, H335

         

4- Methoxyphenol (p- Hydroxyanisole) (CAS No. 150-76-5)
EINECS No. 205-769-8

< 0.01

Acute Toxicity, Oral, Category 4, H302
Eye Irritant, Category 2A, H319
Acute Aquatic Toxicity, Category 3, H402 Chronic Aquatic Toxicity, Category 3, H412

All Luxio products, with the exception of Luxio Base Gel, Luxio Gloss Gel & Luxio Colours - Captive/Current/Diva/ Electric/Expression/Glam/Gold Effects/Legend/Noir/Pink Effects/Posh/Pout/Pure/Purple Effects/Romance/Silver Effects /Swan/Vintage/Vixen, also contain the following chemical:

  

Component

Iron Oxide
CAS No. 1309-37-1 EINECS No. 215-168-2

% (w/w)

< 1.5

GHS Classification

  

None assigned

  

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All Luxio products, with the exception of Luxio Base Gel, Luxio Gloss Gel and Luxio Colours - Allure/Diva/ Electric / Noir, also contain the following chemical:

Component % (w/w) GHS Classification

Titanium Dioxide (CI77891) < 10.0 Carcinogen, Category 2, H351 CAS No. 13463-67-7
EINECS No. 236-675-5

Luxio Colours - Anticipation/Captive/Fantasy/Galaxy/Gold Effects/Inspire/Mystical/Pink Effects/Purple Effects/Silver Effects also contain the following chemical:

Component % (w/w) GHS Classification

Silica < 0.5 None assigned CAS No. 7631-86-9
EINECS No. 231-545-4

Luxio Colours - Cherish/Cremelle/Discretion/Fantasy/Galaxy/Glam/Inspire/Mystical also contain the following chemical:

                

Component % (w/w)

Mica (CI77019) < 1.5 CAS No. 12001-26-2
EINECS No. 310-127-6

Luxio Colours - Noir also contains the following chemical:

Component % (w/w)

Black (CI 77266), Carbon mesoporous < 0.5 CAS No. 1333-86-4
EINECS No. 215-609-9

None assigned

GHS Classification

GHS Classification

         

Other: Warning, may form combustible mixture in air

  

Luxio Colours - Pink Effects also contains the following chemical:

Component % (w/w) GHS Classification

Tin Oxide < 0.1 None assigned CAS No 18282-10-10
EINECS No 242-159-0

4. First Aid Measures

4.1 Description of First Aid Measures

General advice: Consult a physician. Show this safety data sheet to the physician in attendance. Move away from dangerous area. Remove contaminated clothing. Completely decontaminate clothing, shoes and leather goods before re-use or discard.

In case of eye contact: Immediately flush the contaminated eye(s) with lukewarm, gently flowing water for 20 to 30 minutes or until the chemical is removed, while holding the eyelid(s) open. Obtain medical attention immediately or transport to a medical facility and continue to flush the eyes en route.

In case of skin contact: Wash gently and thoroughly with water and non-abrasive soap for at least 20 minutes or until chemical is removed. If signs of sensitization or irritation occur, obtain medical advice.

If inhalation: Remove source of contamination or move victim to fresh air. If breathing is difficult , give artificial respiration. If breathing is difficult oxygen may be beneficial if administered by trained

       

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personnel, preferably on a doctor's advice. DO NOT allow the victim to move about unnecessarily. Consult a physician.

If ingestion: Ingestion unlikely. Never give anything by mouth if victim is rapidly losing consciousness. Have victim rinse mouth thoroughly with water. Do not induce vomiting. Dilute contents of stomach with 240 to 300 ml of water. If vomiting occurs naturally have victim lean forward to reduce risk of aspiration. Seek immediate medical attention.

  1. 4.2  Most important symptoms and effects, both acute and delayed Effects of Short-Term (Acute) Exposure:

    Inhalation: Due to the low volatility of this product, no significant adverse health conditions are expected to occur during the proper use of this product. In rare cases some respiratory irritation may occur.

    Skin Contact: It is expected that absorption through the skin will contribute to overall exposure. Contact with skin may cause an immediate allergic reaction in persons who may be sensitized by previous exposures. Symptoms may include an immediate rash, local redness, or itching of the skin.

    Eye Contact: This product is an eye irritant. Exposure to the eye may cause symptoms which include a burning sensation, tearing, redness and swelling.

    Ingestion: No adverse health effects are expected if a small amount of this product is accidentally ingested.

    Effects of Long-Term (Chronic) Exposure: This product contains ingredients which have been known to cause skin sensitization in some people. Sensitization may occur after prolonged or repeated exposures to this product. Prolonged contact with skin may defat tissue causing dermititis or aggravate existing skin problems.

    Medical Conditions Aggravated By Exposure: Persons susceptable to skin problems may find that the use of this product will cause increased symptoms of existing skin problems.

  2. 4.3  Indication of any immediate medical attention and special treatment needed

    In the event of an allergic reaction, immediate medical help is required. Allergic reactions may result in various health effects including respiration.

    5. Fire Fighting Measures

  1. 5.1  Extinguishing Media
    Suitable extinguishing media: Dry chemical, carbon dioxide, water spray, foam, or water fog.

  2. 5.2  Special hazards arising from mixture: Carbon dioxide, carbon monoxide, oxides of nitrogen, undetermined organic compounds in acrid smoke.

  3. 5.3  Advice for firefighters: Do not enter fire area without proper protection. Fight fire from a safe distance, upwind. Use of water may be ineffective due to low solubility. If water is used, direct fine spray or fog at fire to cool and extinguish flames.

  4. 5.4  Further Information:
    Sensitivity to Impact: No

    Sensitivity to Static Discharge: No

    NATIONAL FIRE PROTECTION ASSOCIATION (NFPA) HAZARD INDEX:

    HEALTH: 3 FLAMMABILITY: 1 REACTIVITY: 0

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6. Accidental Release Measures

  1. 6.1  Personal precautions, protective equipment and emergency procedures

    Respiratory Protection: Vapours will be generated particularly if product is atomized, or heated. If used or sprayed in an enclosed area, at a minimum use a NIOSH approved organic vapour respirator. When cartridge type respirators are used, ensure that the cartridges are changed frequently according to the manufacturer’s recommendations. Respirator selection must be done by a qualified person and be based upon a risk assessment of the work activities and exposure levels. Respirators must be fit tested and users must be clean shaven where the respirator seals to face. Exposure must be kept at or below the applicable exposure limits and the maximum use concentration of the respirator must not be exceeded.

    Skin protection: Depending upon the conditions of use, protective gloves and clothing to prevent skin contact.

    Eye and Face Protection: Chemical splash goggles and/or face shield must be worn when a possibility exists for eye contact due to spashing or spraying liquid. Contact lenses should not be worn.

    Footwear: No specific recommendation.
    Other: Emergency eyes wash fountains should be available in vicinity of use. At minimum, an eye

    lavage kit should be kept on hand.

  2. 6.2  Environmental precautions

    Ensure that any release of this material is contained to prevent leakage into waterways and sanitary sewers.

  3. 6.3  Methods and materials for containment and cleanup
    Remedial Measures: Wash spill area with strong detergent and water solution, rinse with minimal

    water, if possible.

    Large Spills: For large spills, dike area and prevent leakage into waterways or sanitary sewers. Recover using spark proof equipment and store in approved vented containers for re-use or disposal.

    Small Spills: Small spills may be absorbed on an inert medium such as vermiculite or clay, then sweep into vented disposal containers.

  4. 6.4  Referencetoothersections

    For disposal, see section 13

    7. Handling and Storage

  1. 7.1  Precautions for safe handling
    Handling Procedures: Wear proper protective equipment when handling this material. Only use

    non-sparking tools when handling this material.

  2. 7.2  Conditions for safe storage, including incompatibilities

    Storage: Store indoors in a well-ventilated area where the storage temperature can be maintained between 1oC and 38oC. Storage above 38oC will result in reduced product life. Store in tightly closed containers away from heat, sparks, open flame, strong oxidizers, radiation and other initiators. Prevent contamination with foreign materials, including moisture.

  3. 7.3  Specific end use(s)

    No other uses except those mentioned in Section 1.2

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8. Exposure Controls, Personal Protection

  1. 8.1  Control parameters
    Components with workplace control parameters

    Hydroxypropyl Methacrylate, component 2-Methylpropenic Acid, (CAS No. 79-41-4) ACGIH TLV TWA: 20 ppm, eye and skin irritation,

    component Methyloxirane, (CAS No. 75-56-9) ACGIH TLV-TWA: 2 ppm

    4-Methoxyphenol, (CAS No 150-76-5), ACGIH TLV TWA : 5 mg/m3, eye irritation, skin damage

    Black (CI 77266) : No occupational exposure limits reported

    Note: Silica and titanium dioxide have respiratory exposure controls, but since these components are bound into the product and are not capable of becoming airborne, exposure controls need not be listed.

  2. 8.2  Exposure controls

    Engineering Controls: When using indoors, ensure adequate ventilation by using local exhaust. Mechanical ventilation is recommended for all indoor situations to control fugitive emissions. Electrical and mechanical equipment should be explosion proof.

    Respiratory Protection: Vapours will be generated particularly if product is atomized, or heated. If used or sprayed in an enclosed area, at a minimum use a NIOSH approved organic vapour respirator. When cartridge type respirators are used, ensure that the cartridges are changed frequently according to the manufacturer’s recommendations. Respirator selection must be done by a qualified person and be based upon a risk assessment of the work activities and exposure levels. Respirators must be fit tested and users must be clean shaven where the respirator seals to face. Exposure must be kept at or below the applicable exposure limits and the maximum use concentration of the respirator must not be exceeded.

    Skin protection: Depending upon the conditions of use, protective gloves and clothing to prevent skin contact.

    Eye and Face Protection: Chemical splash goggles and/or face shield must be worn when a possibility exists for eye contact due to spashing or spraying liquid. Contact lenses should not be worn.

    Footwear: No specific recommendation.
    Other: Emergency eyes wash fountains should be available in vicinity of use. Control of environmental exposure
    Prevent further leakage or spillage, if safe to do so. Do not let product enter drains.

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9. Physical and Chemical Properties

9.1 Information on basic physical and chemical properties

Appearance: Odour:
Odour Threshold: pH:

Melting Point/Freezing Point: Initial Boiling Point:
Flash Point:
Evaporation Rate: Flammability:

Upper Explosion Limit: Lower Explosion Limit: Vapour Pressure: Vapour Density: Relative Density: Solubility:

Partition Coefficient: Autoignition Temperature: Decomposition Temperature: Viscosity:
Explosive Properties: Oxidizing Properties:

Viscous liquid, various colours Characteristic acrylic odour Not available
Not applicable

0°C 131 oC

>96.7 oC
Negligible
Not flammable
No data
No data
< 0.01 @ 20oC
No data
1.15 @ 25oC (water=1)
Negligible in water
Not available
No data
No data
No data
Not explosive. Not expected to be sensitive to electrostatic discharge. No data

9.2

Other safety information: None
10. Stability and Reactivity

Reactivity

Product may become reactive if inhibitor is depleted.

Chemical Stability

Stable as supplied.

Possibility of hazardous reactions

High temperatures, inhibitor depletion, accidental impurities, or exposure to radiation or oxidizers may initiate spontaneous polymerization, generating heat and pressure. Closed containers may rupture during hazardous polymerization.

Conditions to avoid

Exposure to heat, light and moisture.

Incompatible materials

Keep away from strong oxidizers and moisture.

Hazardous decomposition products

Carbon monoxide, carbon dioxide and various oxides of nitrogen.

10.1 10.2 10.3

10.4 10.5 10.6

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11. Toxicological Information

11.1 Information on toxicological effects

Note to reader: We do NOT test our products on animals. In compliance with current SDS preparation requirements, the values listed are published values for generic ingredients with known animal toxicity.

Acute toxicity Component

Di-Hema Trimethylhexyl Dicarbamate, (CAS No. Proprietory) (EINECS No. None)

2-Hydroxyethyl Methacrylate (HEMA), (CAS No. 868-77-9) ( EINECS No. 212-782-2)

Hydroxypropyl Methacrylate, (CAS No. 27813-02-1)
(EINECS No. 248-666-3)
Trimethylbenzoyl Diphenylphosphine Oxide, (CAS No. 75980-60-8) (EINECS No. 278-355-8)

4- Methoxyphenol (p- Hydroxyanisole), (CAS No. 150-76-5) (EINECS No. 205-769-8)
Iron Oxide, CAS No. 1309-37-1
EINECS No. 215-168-2

Titanium Dioxide, CAS No. 13463-67-7
EINECS No. 236-675-5
Black (CI77266), Carbon, mesoporous, CAS No 1333-86-4 EINECS No 215-609-9
Silica, CAS No. 7631-86-9
EINECS No. 231-545-4
Silica Silylate, CAS No 68909-20-6
Iron Oxide, CAS No. 1309-37-1
EINECS No. 215-168-2
Tin Oxide, CAS No 18282-10-10
EINECS No 242-159-0

LD50

>5000 mg/kg (oral/rat)

5564 mg/kg (oral/rat)
>3000 mg/kg (dermal/rabbit)

11,200 mg/kg (oral/rat)

>5000 mg/kg (oral/rat) >2000 mg/kg (dermal/rabbit)

N/av
>10,000 mg/kg(oral/rat)

>25,000 mg/kg (oral/rat) >10,000 mg/mg (dermal/rabbit) >15,400 mg/kg (oral/rat)

3160 mg/kg (oral/rat)

N/av
>10,000 mg/kg (oral/rat)

>20,000 mg/kg (oral/rat)

LC50

N/av N/av N/av N/av

N/av

N/av

>6820 mg/m3

6750 mg/m3

N/av

N/av N/av

N/av

                                

ABBREVIATION KEY: N/p: not published, N/d: not determined, N/ap: not applicable, N/av: not available Skin corrosion/irritation

Components of this mixture may cause skin irritation, H315, Category 2, Warning

Serious eye damage/eye irritation

Components of this mixture may cause eye irritation, H319, Category 2A, Warning

Respiratory or skin sensitization

Components of this mixture may cause skin sensitization, H317, Category 1, Warning

Germ Cell Mutagenicity

Components in this mixture suspected of causing genetic defects, H341, Category 2, Warning

Carcinogenicity

Not classifiable as a human carcinogen. Titanium dioxide is present in the formulation but is not in a respirable form and cannot become airborne.

Reproductive toxicity

Components in this mixture are suspected of damaging fertility or the unborn child, H361, Category 2, Warning

Specific Target Organ Toxicity – Single exposure

Haigh Industries Inc. - 9 - February 12, 2018

UV/LED Luxio Gels

Components of this mixture may cause respiratory irritation, H335, Category 3, Warning

Specific Target Organ Toxicity – Repeated exposure

No information available

Aspiration Hazard

No information available

Additional information

None

Toxicity To fish:

12.

Ecological Information

No data available

flow through test Fathead Minnow 227mg/l – 96 hour No data available
LC50: rainbow trout – 28.5 mg/l – 96 hour
10 – 100 mg/l

No data available

345 mg/L/72hr (Green algae) > 97 mg/L/72hr (Green algae) No data available
10 – 100 mg/l72 hr

No data available

380 mg/l
>140 mg/l
No data available 10 – 100 mg/l

12.1

12.2

12.3 12.4 12.5 12.6

Dicarbamate
2-Hydroxyethyl methacrylate Hydroxypropyl methacrylate 4-Methoxyphenol Trimethylbenzoyl

diphenylphosphine oxide

To algae:

Di-Hema Trimethylhexyl

Dicarbamate
2-Hydroxyethyl methacrylate Hydroxypropyl methacrylate 4-Methoxyphenol Trimethylbenzoyl

diphenylphosphine oxide

To daphnia:

Di-Hema Trimethylhexyl

Dicarbamate
2-Hydroxyethyl methacrylate Hydroxypropyl methacrylate 4-Methoxyphenol Trimethylbenzoyl

diphenylphosphine oxide

Persistence and degradability

Di-Hema Trimethylhexyl

2-Hydroxyethyl methacrylate (HEMA) and Hydroxypropyl methacrylate (HPMA) are considered to be readily biodegradable.
Trimethylbenzoyl diphenylphosphine oxide is considered to be poorly biodegradable.

Bioaccumulative potential

No data available

Mobility in soil

No data available

Results of PBT and vPvB assessment

Not conducted

Other adverse effects

Haigh Industries Inc.

- 10 -

February 12, 2018

UV/LED Luxio Gels

No data available

13. Disposal Considerations

13.1 Waste treatment methods Product:

Review federal, provincial or state, and local government requirements prior to disposal. Store material for disposal as indicated in Storage Conditions. Disposal by controlled incineration or by secure land fill may be acceptable.

Contaminated packaging

Dispose as above.

14. Transport Information

All Luxio Gels
Transport of Dangerous Goods (TDG and CLR): Not regulated

United States Department of Transport (49CFR): Not regulated International Air Transport Association (IATA): Not regulated International Maritime Organization (IMO): Not regulated

15. Regulatory Information

CANADIAN FEDERAL REGULATIONS:
CEPA, DOMESTIC SUBSTANCES LIST: Listed

UNITED STATES – FEDERAL REGULATIONS:

TOXIC SUBSTANCES CONTROL ACT (TSCA): All components are listed in the inventory. CALIFORNIA Proposition 65, Safe Drinking Water and Toxicity Enforcement Act, 1986: Methyloxirane, component CAS No 75-56-9 of Hydroxypropyl Methacrylate
OSHA, 29 CFR 1910, Subpart Z: Meets criteria for a hazardous substance.

CERCLA, 40 CFR 302: No ingredient listed
SARA 302, 40 CFR 355: Methyloxirane, component CAS No 75-56-9, Rev Date: 2008-11-03 SARA 313, 40 CFR 372: Methyloxirane, component CAS No 75-56-9, Rev Date: 2008-11-03 SARA 311/312, 40 CFR 370: Immediate (Acute) Health, Delayed (Chronic) Health Massachusetts Right to Know: 4- Methoxyphenol (p- Hydroxyanisole), Methyloxirane, New Jersey Right to Know: 4- Methoxyphenol (p- Hydroxyanisole), Methyloxirane, Trimethylbenzoyl Diphenylphosphine Oxide
Pennsylvania Right to Know: 4- Methoxyphenol (p- Hydroxyanisole), Methyloxirane, Trimethylbenzoyl Diphenylphosphine Oxide

 

Haigh Industries Inc. - 11 - February 12, 2018

UV/LED Luxio Gels

16. Other Information

Original Preparation Date: March 17, 2017

Prepared by: KJ Pearson, West Vancouver, BC, V7W 1P3

Disclaimer: This Safety Data Sheet (SDS) was prepared using information provided by CCINFO, ingredient supplier SDS and other relevant sources. This product has been classified using weight of evidence, expert judgment and previous testing as per Part 1.3 of the Fifth Edition of The Globally Harmonized System of Classification and Labelling of Chemicals (GHS). The information in this SDS is offered for your consideration and guidance when exposed to this product. Haigh Industries Inc. expressly disclaims all expressed or implied warranties and assumes no responsibilities for the accuracy or completeness of the data contained herein. The data in this SDS does not apply to use with any other product or in any other process.

This Safety Data Sheet may not be changed, or altered in any way without the expressed knowledge and permission of Haigh Industries Inc.

Revisions: February 12, 2018: Formulation change eliminating the ingredient, 1-Methyl-2-pyrrolidone

Haigh Industries Inc. - 12 - February 12, 2018

Prep & Wipe


SDS Preparation Date (dd/mm/yyyy): 23/09/2013

SAFETY DATA SHEET

Haigh Industries Inc. #5 - 8118 North Fraser Way Burnaby, British Columbia, Canada V5J 0E5 Telephone: 001-604-278-5851 Fax: 001-604-278-5871

Product code(s): Solvents Page 1 of 11

This safety data sheet complies with the requirements of Regulation (EC) No. 1907/2006.

SECTION 1. IDENTIFICATION OF THE SUBSTANCE / MIXTURE AND OF THE COMPANY / UNDERTAKING

Product identifier : Prep & Wipe Product Code(s) : Solvents

Relevant identified uses of the substance or mixture and uses advised against : Cosmetic nail cleansing agent.

Use pattern: Consumers.

Details of the supplier of the safety data sheet:

Haigh Industries Inc.

#5 – 8118 North Fraser Way Burnaby, British Columbia, Canada V5J 0E5
Email: hind@telus.net

Telephone : 001-604-278-5851 Emergency Telephone Number

: 001-352-323-3500 (INFOTRAC - Contract # 103390) SECTION 2. HAZARDS IDENTIFICATION

Classification of the substance or mixture

Clear liquid. Alcohol odour.

Most important hazards:
This mixture is classified as hazardous in accordance with Regulation (EC) No 1272/2008. Hazardous classification:

Flammable liquid - Category 2; H225
Eye damage/irritation - Category 2; H319
STOT - single exposure - Category 3; H336
EUH066 - Repeated exposure may cause skin dryness or cracking.

The preparation is classified as dangerous in accordance with Directive 1999/45/EC. Classification: F - Highly flammable

R11 - Highly flammable. Xi - Irritant

R36 - Irritating to eyes.
R66 - Repeated exposure may cause skin dryness or cracking. R67 - Vapours may cause drowsiness and dizziness.

Label elements

Signal word:

Danger!

Hazard statements:

H225 - Highly flammable liquid and vapour H319 - Causes serious eye irritation.
H336 - May cause drowsiness or dizziness.

Supplemental Hazard Statements:

EUH066 - Repeated exposure may cause skin dryness or cracking.

 

Prep & Wipe
SDS Preparation Date (dd/mm/yyyy): 23/09/2013

SAFETY DATA SHEET

Haigh Industries Inc. #5 - 8118 North Fraser Way Burnaby, British Columbia, Canada V5J 0E5 Telephone: 001-604-278-5851 Fax: 001-604-278-5871

Product code(s): Solvents Page 2 of 11

This safety data sheet complies with the requirements of Regulation (EC) No. 1907/2006.

Precautionary statements:

P102 - Keep out of reach of children.
P210 - Keep away from heat and open flames. - No Smoking.
P261 - Avoid breathing vapours.
P280 - Wear protective gloves and eye/face protection.
P303 + P361 + P353 - IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower. P305 + P351 + P338 - IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and

easy to do. Continue rinsing.
P304+P340 - IF INHALED: Remove person to fresh air and keep comfortable for breathing.

P312 - Call a POISON CENTER or doctor/physician if you feel unwell. P501 - Dispose of contents/container in accordance with local regulation.

Hazard pictograms:

Other hazards

Other hazards which do not result in classification:
Burning produces obnoxious and toxic fumes. Mild respiratory irritant Ingestion may cause gastrointestinal irritation, nausea, vomiting and diarrhea.

Environmental precautions:
Avoid release to the environment. See ECOLOGICAL INFORMATION, Section 12.

PBT assessment:
This substance is not considered to be persistent, bioaccumulating nor toxic (PBT).

SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS

Substances

Not applicable

Mixtures

Chemical nature - Mixture of: Alcohol; Esters; Fragrances.
The following substances shall be indicated according to legislation:

 

Chemical name

CAS #

EC No.

Concentration

EU Classification

CLP Classification

Isopropyl alcohol

67-63-0

200-661-7

80.0 - 100.0

F - Highly flammable; R11 Xi - Irritant; R36
R67

Flam. Liq. 2; H225 Eye Irrit. 2; H319 STOT SE 3; H336

Ethyl acetate

141-78-6

205-500-4

7.0 - 13.0

F - Highly flammable; R11 Xi - Irritant; R36
R66
R67

Flam. Liq. 2; H225 Eye Irrit. 2; H319 STOT SE 3; H336 EUH066

For the full text of the H and R phrases not mentioned in this Section or in Section 2, see Section 16.

 

Prep & Wipe
SDS Preparation Date (dd/mm/yyyy): 23/09/2013

SAFETY DATA SHEET

Haigh Industries Inc. #5 - 8118 North Fraser Way Burnaby, British Columbia, Canada V5J 0E5 Telephone: 001-604-278-5851 Fax: 001-604-278-5871

Product code(s): Solvents Page 3 of 11

This safety data sheet complies with the requirements of Regulation (EC) No. 1907/2006.

SECTION 4. FIRST-AID MEASURES

Description of first aid measures Ingestion :

Inhalation :

Do NOT induce vomiting. Never give anything by mouth to an unconscious person. When symptoms persist or in all cases of doubt seek medical advice.
IF INHALED: Remove person to fresh air and keep comfortable for breathing. Call a POISON CENTRE or doctor/physician if you feel unwell.

IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower. When symptoms persist or in all cases of doubt seek medical advice.
IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists, get medical advice/attention.

Skin contact Eye contact

: :

Most important symptoms and effects, both acute and delayed : Causes serious eye irritation.

May cause drowsiness and dizziness.
Repeated exposure may cause skin dryness or cracking.
Mild respiratory irritant
Ingestion may cause gastrointestinal irritation, nausea, vomiting and diarrhea.

Indication of any immediate medical attention and special treatment needed : Treat symptomatically.

SECTION 5. FIRE-FIGHTING MEASURES

Extinguishing media

Suitable extinguishing media

: Carbon dioxide (CO2); Dry chemical; Alcohol-resistant foam. Unsuitable extinguishing media

: Water may cause spattering of hot material and may spread burning. Special hazards arising from the substance or mixture

: Highly flammable liquid and vapour. May be ignited by open flame. Vapours are heavier than air and may spread along floors. The pressure in sealed containers can increase under the influence of heat. Burning produces obnoxious and toxic fumes. In the event of fire the following can be released: Carbon oxides; unburned alcohols; Other unidentified organic compounds.

Advice for firefighters

Protective equipment for fire-fighters

  • :  Wear self-contained breathing apparatus and protective suit. Fight fire with normal precautions from a reasonable distance.

    Special fire-fighting procedures

  • :  Move containers from fire area if safe to do so. Cool closed containers exposed to fire with water spray. Do not allow run-off from fire fighting to enter drains or water courses. Dike for water control.

    SECTION 6. ACCIDENTAL RELEASE MEASURES

    Personal precautions, protective equipment and emergency procedures

    : Wear suitable protective equipment. Keep people away from and upwind of spill/leak. Restrict access to area until completion of clean-up.

    Environmental precautions : Do not allow material to contaminate ground water system. If necessary, dike well ahead of the spill to prevent runoff into drains, sewers, or any natural waterway or drinking supply.

 

Prep & Wipe
SDS Preparation Date (dd/mm/yyyy): 23/09/2013

SAFETY DATA SHEET

Haigh Industries Inc. #5 - 8118 North Fraser Way Burnaby, British Columbia, Canada V5J 0E5 Telephone: 001-604-278-5851 Fax: 001-604-278-5871

Product code(s): Solvents Page 4 of 11

This safety data sheet complies with the requirements of Regulation (EC) No. 1907/2006.

Methods and material for containment and cleaning up

Reference to other sections

  • :  Ventilate the area. Remove all sources of ignition. Prevent further leakage or spillage if safe to do so. Use only non-sparking tools. Soak up with inert absorbent material. Do not use combustible absorbents, such as sawdust. Pick up and transfer to properly labelled containers. Contaminated absorbent material may pose the same hazards as the spilled product. Contact the proper local authorities.

  • :  Refer to protective measures listed in sections 7 and 8. Refer to Section 13 for disposal of contaminated material.

SECTION 7. HANDLING AND STORAGE

Precautions for safe handling

: Wear protective gloves and eye/face protection. Use only in well-ventilated areas. Avoid breathing vapours. Avoid contact with skin, eyes and clothing. Keep away from heat and open flames. - No smoking. Keep container tightly closed. Ground/Bond container and receiving equipment. Use only non-sparking tools. Take precautionary measures against static discharge. Empty containers retain residue (liquid and/or vapour) and can be dangerous. Wash thoroughly after handling.

Conditions for safe storage, including any incompatibilities
: Store in cool/well-ventilated place. Store locked up. Inspect periodically for damage or leaks.

No smoking. Protect from sunlight. Keep out of the reach of children. Specific end use(s) : Cosmetic nail cleansing agent.

SECTION 8. EXPOSURE CONTROLS / PERSONAL PROTECTION

Control Parameters

Exposure Limits:

 

Chemical Name

Exposure Limits

Type

Notes

  

Ethyl acetate

400 ppm (1400 mg/m3) (TWA)

400 ppm (1500 mg/m3) (TWA)

400 ppm (1400 mg/m3) (TWA)

200 mg/m3 (TWA) 600 mg/m3 (STEL)

France (OEL)

Germany (OEL)

Greece (OEL)

Poland (OEL)

None.

(exposure factor 2)

None.

None.

Isopropyl alcohol

400 ppm (1460 mg/m3) (TWA)

200 ppm (TWA) 400 ppm (STEL)

400 ppm (980 mg/m3) (STEL)

200 ppm (500 mg/m3) (TWA)

400 ppm (980 mg/m3) (TWA) 500 ppm (1225 mg/m3) (STEL)

900 mg/m3 (TWA) 1200 mg/m3 (STEL)

200 ppm (500 mg/m3) (TWA) 400 ppm (1000 mg/m3) (STEL)

Spain (OEL)

The United Kingdom (WELs)

France (OEL)

Germany (OEL)

Greece (OEL)

Poland (OEL)

Spain (OEL)

None.

None.

None.

(exposure factor 2)

None.

Skin notation

None.

400 ppm (999 mg/m3) (TWA) The United Kingdom (WELs) None. 500 ppm (1250 mg/m3) (STEL)

        

 

Prep & Wipe
SDS Preparation Date (dd/mm/yyyy): 23/09/2013

SAFETY DATA SHEET

Haigh Industries Inc. #5 - 8118 North Fraser Way Burnaby, British Columbia, Canada V5J 0E5 Telephone: 001-604-278-5851 Fax: 001-604-278-5871

Product code(s): Solvents Page 5 of 11

This safety data sheet complies with the requirements of Regulation (EC) No. 1907/2006.

Exposure controls
Ventilation and engineering measures

: Use only in well-ventilated areas. Apply technical measures to comply with the occupational exposure limits. Where reasonably practicable this should be achieved by the use of local exhaust ventilation and good general extraction. Use explosion-proof equipment. In case of insufficient ventilation wear suitable respiratory equipment.

Respiratory protection :

Skin protection :

Eye / face protection :

Other protective equipment : General hygiene considerations

In the case of vapour formation use a respirator with an approved filter. The filter class for the respirator must be suitable for the maximum expected contaminant concentration (gas/vapour/aerosol/particulates) that may arise when handling the product. If this concentration is exceeded, self-contained breathing apparatus must be used.

Wear protective gloves. The suitability for a specific workplace should be discussed with the producers of the protective gloves. The selected protective gloves have to satisfy the specifications of EU Directive 89/689/EEC and the standard EN 374 derived from it. Wear as appropriate: Butyl rubber; Barrier; etc.

Wear sufficient clothing to prevent skin contact.
Wear eye/face protection. If splashes are likely to occur, wear: Tightly fitting safety goggles.

A full face shield may also be necessary. See also EN 166.
Ensure that eyewash stations and safety showers are close to the workstation location.

: Avoid breathing mist or vapours. Avoid contact with skin, eyes and clothing. Do not eat, drink or smoke when using this product. Wash thoroughly after handling. Remove and wash contaminated clothing before re-use.

SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES

Information on basic physical and chemical properties

Appearance : Odour : Odour threshold : pH: Flash point : Flashpoint (Method) : Lower flammable limit (% by vol.)

: Upper flammable limit (% by vol.)

Clear liquid.
Alcohol odour.
No information available.
No information available.
- 4.4 to 12°C (based on ingredients) Tag closed cup (based on ingredients)

2.0% (based on ingredients)

12.0% (based on ingredients) Not applicable.
399°C (based on ingredients) No information available. None known.

May be sensitive to static discharge. Vapours in the flammable range may be ignited by a static discharge of sufficient energy. Not expected to be sensitive to mechanical impact.

Flammability (solid, gas) Auto-ignition temperature Decomposition temperature Oxidizing properties Explosive properties

: : : : : :

Initial boiling point and boiling range

Melting/Freezing point Relative density Solubility in water Other solubility(ies) Vapour pressure

: 77.5 - 82.3°C
: - 88.5°C (Freezing point)
: 0.795 @ 25°C
: completely soluble
: Soluble in most organic solvents (e.g. ethanol, acetone, diethyl ether, chloroform). : 4.41 - 9.73 kPa @ 20°C

 

Prep & Wipe
SDS Preparation Date (dd/mm/yyyy): 23/09/2013

SAFETY DATA SHEET

Haigh Industries Inc. #5 - 8118 North Fraser Way Burnaby, British Columbia, Canada V5J 0E5 Telephone: 001-604-278-5851 Fax: 001-604-278-5871

Product code(s): Solvents Page 6 of 11

This safety data sheet complies with the requirements of Regulation (EC) No. 1907/2006.

Vapour density : 2.07 (Air = 1.0) Partition coefficient: n-octanol/water

: Viscosity : Evaporation rate (BuAe = 1) :

Other Information

Log P(oct) = 0.05
No information available. 6.2

No information available.

Volatiles (% by weight) : Volatile organic Compounds (VOC's)

: No information available. Other physical/chemical comments

: No additional information.

SECTION 10. STABILITY AND REACTIVITY

Reactivity : Not normally reactive.

: Stable under normal conditions. Possibility of hazardous reactions

: Hazardous polymerization does not occur. In the presence of water, product may slowly hydrolyze to ethyl alcohol and acetic acid.

Conditions to avoid : Direct sources of heat. Do not use in areas without adequate ventilation. Avoid contact with incompatible materials. Avoid moisture.

Incompatible materials : Strong oxidizing agents; Water; Reactive metals; Corrosives. Hazardous decomposition products

: Burning produces obnoxious and toxic fumes. In the event of fire the following can be released: Carbon oxides; unburned alcohols; Other unidentified organic compounds.

SECTION 11. TOXICOLOGICAL INFORMATION

Information on Toxicological effects:

Chemical stability

Acute toxicity :

Skin corrosion/Irritation
Serious eye damage/irritation :

Respiratory or skin sensitisation

According to the classification criteria of the European Union, this product is not considered as being an acutely toxic chemical.

Germ cell mutagenicity Carcinogenicity Reproductive toxicity STOT-single exposure

STOT-repeated exposure Aspiration hazard

  • :  According to the classification criteria of the European Union, this product is not considered as being an allergic respiratory sensitiser.
    According to the classification criteria of the European Union, this product is not considered as being an allergic skin sensitiser.

  • :  Contains no ingredient listed as a mutagen.

  • :  Contains no ingredient listed as a carcinogen.

  • :  Contains no ingredient listed as toxic to reproduction.

  • :  This substance is classified as hazardous according to Regulation (EC) No. 1272/2008. Classification:
    Specific target organ toxicity - single exposure - Category 3. May cause drowsiness and dizziness.

  • :  According to the classification criteria of the European Union, this product is not expected to cause target organ toxicity through repeated exposures.

  • :  According to the classification criteria of the European Union, this product is not considered as being an aspiration hazard to humans.

: According to the classification criteria of the European Union, the product is not considered as being a skin irritant.

This substance is classified as hazardous according to Regulation (EC) No. 1272/2008. Classification:
Eye damage/irritation - Category 2. Causes serious eye irritation.

 

Prep & Wipe
SDS Preparation Date (dd/mm/yyyy): 23/09/2013

Haigh Industries Inc. #5 - 8118 North Fraser Way Burnaby, British Columbia, Canada V5J 0E5 Telephone: 001-604-278-5851 Fax: 001-604-278-5871

Product code(s): Solvents Page 7 of 11

Toxicological data

Routes of exposure Effects of acute exposure

See below for

SAFETY DATA SHEET

This safety data sheet complies with the requirements of Regulation (EC) No. 1907/2006.

: There is no available data for the product itself, only for the ingredients. individual ingredient acute toxicity data.

Chemical name

LC50(4hr) inh, rat

(Oral, rat)

(Rabbit, dermal)

12 890 mg/kg > 18 000 mg/kg

LD50

   

Isopropyl alcohol

Ethyl acetate

17 000 ppm (41.8 mg/L)

8000 - 16 000 ppm (28.8 - 57.7 mg/L)

4720 mg/kg

5620 mg/kg

  

  • :  Eye contact; Skin contact; Inhalation; Ingestion.

  • :  Inhalation: Vapours may cause drowsiness and dizziness. Mild respiratory irritant

    Skin contact: Direct skin contact may cause slight or mild, transient irritation. Effects of excessive exposures may include: stinging; Redness.

    Eye contact: Causes serious eye irritation. May cause moderate to severe irritation. Causes redness, tearing and blurred vision.

    Ingestion: Ingestion may cause gastrointestinal irritation, nausea, vomiting and diarrhea. Ingestion of larger amounts may cause defects to the central nervous system (e.g. dizziness, headache).

Potential Chronic Health Effects
: Repeated exposure may cause skin dryness or cracking.

Other important hazards : None reported by the manufacturer. SECTION 12. ECOLOGICAL INFORMATION

Ecotoxicity : Should not be released into the environment. No data is available on the product itself. See the following tables for individual ingredient ecotoxicity data.

Ecotoxicity data:

Ingredients

CAS No

Toxicity to Fish

LC50 / 96h

NOEC / 21 day

M Factor

Isopropyl alcohol

67-63-0

9640 mg/L (Fathead minnow) (OECD)

No information available.

None.

Ethyl acetate

141-78-6

230 mg/L (Fathead minnow) (OECD)

No information available.

None.

Ingredients

CAS No

Toxicity to Daphnia

EC50 / 48h

NOEC / 21 day

M Factor

Isopropyl alcohol

67-63-0

1400 mg/L (Daphnia magna) (OECD)

30 mg/L (OECD)

None.

Ethyl acetate

141-78-6

717 mg/L (Daphnia magna) (IUCLID)

No information available.

None.

 

Prep & Wipe
SDS Preparation Date (dd/mm/yyyy): 23/09/2013

SAFETY DATA SHEET

Haigh Industries Inc. #5 - 8118 North Fraser Way Burnaby, British Columbia, Canada V5J 0E5 Telephone: 001-604-278-5851 Fax: 001-604-278-5871

Product code(s): Solvents Page 8 of 11

This safety data sheet complies with the requirements of Regulation (EC) No. 1907/2006.

Ingredients

CAS No

Toxicity to Algae

EC50 / 96h or 72h

NOEC / 96h or 72h

M Factor

Isopropyl alcohol

67-63-0

> 1000 mg/L/72hr (Green algae) (IUCLID)

No information available.

None.

Ethyl acetate

141-78-6

> 100 mg/L/72hr (Green algae) (OECD)

No information available.

None.

Persistence and degradability

Bioaccumulation potential
Mobility in soil
Results of PBT and vPvB assessment

: The product itself has not been tested.
The following ingredients are considered to be readily biodegradable: Isopropyl alcohol; Ethyl acetate.

: The product itself has not been tested.

: The product itself has not been tested.

: This substance is not considered to be persistent, bioaccumulating nor toxic (PBT). Other Adverse Environmental effects

: None known. Water contaminating class (Germany)

: 1 (self classified) SECTION 13. DISPOSAL CONSIDERATIONS

Waste Treatment Methods:

Handling for Disposal Methods of Disposal

  • :  Handle in accordance with good industrial hygiene and safety practice. Refer to protective measures listed in sections 7 and 8.

  • :  Dispose of in accordance with the European Directives on waste and hazardous waste. Waste must be classified and labelled prior to recycling or disposal. According to the European Waste Catalogue, Waste Codes are not product specific, but application specific. Waste codes should be assigned by the user based on the application for which the product was used.

SECTION 14. TRANSPORTATION INFORMATION

Regulatory Information

ADR/RID

EU ADR/RID Classification Code

UN Number

UN1993

UN proper shipping name

FLAMMABLE LIQUID, N.O.S. (Isopropyl alcohol; Ethyl acetate)

Transport hazard class(es)

3

Packing Group

Label

EU ADR / RID Hazard Identification Number

ADR/RID Additional information

F1 - Flammable liquids having a flash-point of or below 60 °C

May be shipped

as LIMITED QUANTITY when transported in containers no lar

ger than 1.0 Litr

II

33 - highly flammable liquid (flash-point below 23°C)

e, in packag

es not exceeding

30 kg gross mass.

     

 

Prep & Wipe
SDS Preparation Date (dd/mm/yyyy): 23/09/2013

SAFETY DATA SHEET

Haigh Industries Inc. #5 - 8118 North Fraser Way Burnaby, British Columbia, Canada V5J 0E5 Telephone: 001-604-278-5851 Fax: 001-604-278-5871

Product code(s): Solvents Page 9 of 11

This safety data sheet complies with the requirements of Regulation (EC) No. 1907/2006.

Special precautions for user : Appropriate advice on safety must accompany the package. Keep away from heat, sparks and open flame. - No smoking.

Environmental hazards : This product does not meet the criteria for an environmentally hazardous mixture, according to the IMDG Code. See ECOLOGICAL INFORMATION, Section 12.

Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code : Not applicable.

SECTION 15. REGULATORY INFORMATION

Safety, health and environmental regulations/legislation specific for the substance or mixture

ICAO/IATA

ICAO/IATA Additional information

UN1993

Flammable liquid, n.o.s. (Isopropyl alcohol; Ethyl acetate)

3

II

Refer to the app

ropriate Packing Instruction, prior to shipping this material. Re

view all State an

d Operator

Variations, prior to

shipping this material.

IMDG

IMDG Additional information

UN1993

FLAMMABLE LIQUID, N.O.S. (Isopropyl alcohol; Ethyl acetate)

3

II

May be shipped

as LIMITED QUANTITY when transported in containers no lar

ger than 1.0 Litr

e, in packag

es not exceeding

30 kg gross mass.

Chemical safety assessment

: 1. Substances presenting a physical, health or environmental hazard within the meaning of Regulation (EC) No. 1272/2008.

2. Classification according to Regulation (EC) No. 1272/2008 on the classification of hazardous mixtures.

3. This safety data sheet complies with the requirements of Regulation (EC) No. 1907/2006. 4. In accordance with the legislation of the United Kingdom.
5. German legislation on water endangering substances VwVwS (see Section 12)

: A chemical safety assessment has not been carried out by the Manufacturer of this product.

 

Prep & Wipe
SDS Preparation Date (dd/mm/yyyy): 23/09/2013

SAFETY DATA SHEET

Haigh Industries Inc. #5 - 8118 North Fraser Way Burnaby, British Columbia, Canada V5J 0E5 Telephone: 001-604-278-5851 Fax: 001-604-278-5871

Product code(s): Solvents Page 10 of 11

This safety data sheet complies with the requirements of Regulation (EC) No. 1907/2006.

SECTION 16. OTHER INFORMATION

Legend :

ADR: European Agreement concerning the International Carriage of Dangerous Goods by Road
CAS: Chemical Abstract Services
CLP: Regulation (EC) No 1272/2008 on classification, labelling and packaging of substances and mixtures

EC: European Community
EEC: European Economic Community
EINECS: European Inventory of Existing Commercial chemical Substances EN: European Standard
EU: European Union
HSDB: Hazardous Substances Data Bank
IATA: International Air Transport Association
IBC: Intermediate Bulk Container

Information Source

Preparation Date (dd/mm/yyyy)

:

: :

OECD: Organisation for Economic Co-operation and Development
OEL: National occupational exposure limits
RID: Regulations concerning the International Carriage of Dangerous Goods by Rail RTECS: Registry of Toxic Effects of Chemical Substances
SDS: Safety Data Sheet
STEL: Short Term Exposure Limit
TWA: Time Weighted Average
WEL: Workplace Exposure Limit

1. Material Safety Data Sheet from manufacturer.
2. Canadian Centre for Occupational Health and Safety, CCInfoWeb Databases, 2013

(Chempendium, RTECs, HSDB, INCHEM).
3. European Chemicals Bureau, Existing Chemicals Work Area, EINECS Information

System, 2013.
4. European Chemicals Agency, Classification Legislation, 2013.
5. OECD - The Global Portal to Information on Chemical Substances - eChemPortal, 2013.

23/09/2013 Not applicable.

handling

Provide adequate information, instruction and training for operators.
This product is subject to the EEC Directive for Cosmetics, 76/768/EEC, and its National implementations in the European Union. This product may also contain the following chemicals:
Fragrance.

H & R-Phrases (Full text)
Other special considerations for :

ICAO:
IMDG:
IUCLID:
LC: Lethal Concentration LD: Lethal Dose

International Civil Aviation Organisation International Maritime Dangerous Goods

International Uniform ChemicaL Information Database

 

Prep & Wipe
SDS Preparation Date (dd/mm/yyyy): 23/09/2013

SAFETY DATA SHEET

Haigh Industries Inc. #5 - 8118 North Fraser Way Burnaby, British Columbia, Canada V5J 0E5 Telephone: 001-604-278-5851 Fax: 001-604-278-5871

Product code(s): Solvents Page 11 of 11

This safety data sheet complies with the requirements of Regulation (EC) No. 1907/2006.

DISCLAIMER

This Safety Data Sheet was prepared by Haigh Industries Inc. using information provided by Parker Hannifin Corporation and CCOHS’ Web Information Service. The information in the Safety Data Sheet is offered for your consideration and guidance when exposed to this product. ICC The Compliance Center Inc and Haigh Industries Inc. expressly disclaim all expressed or implied warranties and assume no responsibilities for the accuracy or completeness of the data contained herein. The data in this SDS does not apply to use with any other product or in any other process.

This Safety Data Sheet may not be changed, or altered in any way without the expressed knowledge and permission of ICC The Compliance Center Inc. and Haigh Industries Inc.

END OF DOCUMENT

Prepared for:

Haigh Industries Inc.
#5 - 8118 North Fraser Way
Burnaby, British Columbia, Canada, V5J 0E5 Telephone: 001-604-278-5851http://www.haighindustries.com
Direct all enquiries to Haigh Industries.

 

Prepared by:

ICC The Compliance Center Inc.

http://www.thecompliancecenter.com

SDS - Shine On, Matte On, Black On, White On

Shine On, Matte On, Black On, White On

 

SAFETY DATA SHEET

This Safety Data Sheet complies with the Canadian Controlled Product Regulations, the United States Occupational Safety and Health

Administration (OSHA) Hazard Communication Standard, 29 CFR 1910 (OSHA HCS), and the European Union Directives.

1. Product and Supplier Identification

1.1 Product: Shine On, Matte On, Black On, White On

  1. 1.2  Product Use:

  2. 1.3  Producer:

    Supplier:

  3. 1.4  Emergencies (24-hour number): +1(604) 278-5851

    2. Hazards Identification

2.1 Classification of product or mixture

Note to reader: This product in an untested mixture and GHS classification is based on the classification of the ingredients and their concentrations. Proprietary ingredients do NOT exhibit any health effects not listed in this SDS.

Nail Gel

Haigh Industries Inc.,
#5 – 8118 North Fraser Way, Burnaby, B.C.
Canada, V5J 0E5

Telephone: (604) 278-5851

As above

GHS Classification:

Skin Irritation: Category 2
Eye Irritation: Category 2A
Skin Sensitization: Category 1
Specific Target Organ Toxicity, Single Exposure, Category 3 Germ Cell Mutagenicity: Category 2
Reproductive Toxicity: Category 2

2.2 GHS Label Elements, including precautionary statements Pictogram:

 

Signal Word: Warning GHS Hazard Statements:

H315: Causes skin irritation.
H317: May cause an allergic skin reaction.
H319: Causes serious eye irritation.
H335: May cause respiratory irritation.
H341: Suspected of causing genetic defects.
H361: Suspected of damaging fertility or the unborn child.

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GHS Precautionary Statements:

Prevention:

Response:

P201: Obtain special instructions before use.
P202: Do not handle until all safety precautions have been read and

understood.
P261: Avoid breathing mist, vapours or spray
P264: Wash skin thoroughly after handling.
P271: Use only outdoors or in a well-ventilated area.
P272: Contaminated work clothing should not be allowed out of

the workplace.
P280: Wear protective gloves/protective clothing/eye

protection/face protection.

P302+P352: IF ON SKIN: Wash with plenty of soap and water. P304+P340: IF INHALED: Remove person to fresh air and keep

comfortable for breathing.
P305+P351+P338: IF IN EYES: Rinse cautiously with water for

several minutes. Remove contact lenses, if present and

easy to do. Continue rinsing.
P308+P313: IF exposed or concerned: Get medical advice/attention. P312: Call a POISON CENTER/doctor...if you feel unwell.
P321: Specific treatment (see Section 4).
P332+ P313: If skin irritation occurs: Get medical advice/attention. P333+P313: If skin irritation or rash occurs, get medical advice/attention P337+P313: If skin irritation or rash occurs: Get medical

advice/attention.
P362 + P364: Take off contaminated clothing and wash it before reuse.

P403+P233: Store in a well-ventilated place. Keep container tightly closed.

P405: Store locked up.

P501: Dispose of contents/container to an approved waste disposal plant.

Storage:

Disposal:

  1. 2.3  Hazards not otherwise classified (HNOC) or not covered by GHS: None

  2. 2.4  Additional Information

    Primary Routes of Entry:

    Skin Contact: Yes Skin Absorption: Yes Eye Contact: Yes Ingestion: No Inhalation: Yes

    Emergency Overview: This product contains ingredients which may cause mild eye and skin irritation in some people. For eye contact, symptoms may include a moderate burning sensation, tearing, redness, or swelling. Contact with skin may cause an allergic reaction due to prior sensitization. Local redness, rash, or itchy skin may occur in those persons with a pre-existing sensitivity or those predisposed to skin problems. In rare cases an allergic skin reaction may occur after long term contact with this product.

    Effects of Short-Term (Acute) Exposure:

    Inhalation: Due to the low volatility of this product, no significant adverse health conditions are expected to occur during the proper use of this product. In rare cases some respiratory irritation may occur.

    Skin Contact: It is expected that absorption through the skin will contribute to overall exposure. Contact with skin may cause an immediate allergic reaction in persons who may be sensitized by

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previous exposures. Symptoms may include an immediate rash, local redness, or itching of the skin.

Eye Contact: This product is an eye irritant. Exposure to the eye may cause symptoms which include a burning sensation, tearing, redness and swelling.

Ingestion: No adverse health effects are expected if a small amount of this product is accidentally ingested.

Effects of Long-Term (Chronic) Exposure: This product contains ingredients which have been known to cause skin sensitization in some people. Sensitization may occur after prolonged or repeated exposures to this product. Prolonged contact with skin may defat tissue causing dermititis or aggravate existing skin problems.

Medical Conditions Aggravated By Exposure: Persons susceptable to skin problems may find that the use of this product will cause increased symptoms of existing skin problems.

3. Composition

3.1 Mixture composition

Shine On, Black On, White On and Matte On all contain the following chemicals:

  

Component

2-Hydroxyethyl Methacrylate (HEMA) CAS No. 868-77-9
EINECS No. 212-782-2 Hydroxypropyl Methacrylate

CAS No. 27813-02-1 EINECS No. 248-666-3

Non-hazardous ingredients and ingredients below disclosure requirements.

% (w/w)

5 - 11 4 - 10

None

GHS Classification

Skin Irritant, Category 2, H315
Skin Sensitizer, Category 1, H317
Eye Irritant, Category 2A, H319
Skin Sensitizer, Category 1, H317
Eye Irritant, Category 2A, H319
Germ Cell Mutagenicity, Category 2, H341

Di-Hema Trimethylhexyl Dicarbamate CAS No. Not reported
EINECS No. Not reported

60 - 70

Skin Irritant, Category 2, H315 Skin Sensitizer, Category 1, H317 Eye Irritant, Category 2A, H319 STOT-SE, Category 3, H335

  

4- Methoxyphenol (p- Hydroxyanisole) (CAS No. 150-76-5)
(EINECS No. 205-769-8)

< 0.01

Acute Toxicity, Oral, Category 4, H302
Eye Irritant, Category 2A, H319
Acute Aquatic Toxicity, Category 3, H402 Chronic Aquatic Toxicity, Category 3, H412

N/ap

  

Shine On, Black On, White On also contain the following chemicals:

  

Component

PEG-4 Dimethylacrylate
CAS No 109-17-1
EINECS No.203-653-1
Trimethylbenzoyl Diphenylphosphine Oxide CAS No. 75980-60-8

EINECS No. 278-355-8

Matte On also contains the following chemical:

Component

Silica Silylate
(CAS No. 68909-20-6) EINECS No. Not known Polypropylene

% (w/w)

15 - 25 1 - 2

% (w/w)

0.2 – 1.0 5-10

GHS Classification

Skin Irritant, Category 2, H315
Skin Sensitizer, Category 1, H317
Eye Irritant, Category 2A, H319 Reproductive Hazard, Category 2, H361 Chronic Aquatic Toxicity, Category 3, H412

GHS Classification

Not classified as hazardous None assigned

                

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CAS No. 9003-07-0

White On also contains the following chemical:

Component

Titanium Dioxide (CI77891) CAS No. 13463-67-7 EINECS No. 236-675-5 Silica

CAS No. 7631-86-9 EINECS No. 231-545-4

% (w/w)

7.0 -10.0 0.1 – 0.5

GHS Classification

Carcinogen, Category 2, H351 None assigned

           

These products may also contain the following pigments: Iron Oxide, (CI77499), CAS No 12227-89-3
Violet 2 (CI 60725), CAS No 81-48-1

4. First Aid Measures

  1. 4.1  Description of First Aid Measures

    General advice: Consult a physician. Show this safety data sheet to the physician in attendance. Move away from dangerous area. Remove contaminated clothing. Completely decontaminate clothing, shoes and leather goods before re-use or discard.

    In case of eye contact: Immediately flush the contaminated eye(s) with lukewarm, gently flowing water for 20 to 30 minutes or until the chemical is removed, while holding the eyelid(s) open. Obtain medical attention immediately or transport to a medical facility and continue to flush the eyes en route.

    In case of skin contact: Wash gently and thoroughly with water and non-abrasive soap for at least 20 minutes or until chemical is removed. If signs of sensitization or irritation occur, obtain medical advice.

    If inhalation: Remove source of contamination or move victim to fresh air. If breathing is difficult , give artificial respiration. If breathing is difficult oxygen may be beneficial if administered by trained personnel, preferably on a doctor's advice. DO NOT allow the victim to move about unnecessarily. Consult a physician.

    If ingestion: Ingestion unlikely. Never give anything by mouth if victim is rapidly losing consciousness. Have victim rinse mouth thoroughly with water. Do not induce vomiting. Dilute contents of stomach with 240 to 300 ml of water. If vomiting occurs naturally have victim lean forward to reduce risk of aspiration. Seek immediate medical attention.

  2. 4.2  Most important symptoms and effects, both acute and delayed Effects of Short-Term (Acute) Exposure:

    Inhalation: Due to the low volatility of this product, no significant adverse health conditions are expected to occur during the proper use of this product. In rare cases some respiratory irritation may occur.

    Skin Contact: It is expected that absorption through the skin will contribute to overall exposure. Contact with skin may cause an immediate allergic reaction in persons who may be sensitized by previous exposures. Symptoms may include an immediate rash, local redness, or itching of the skin.

    Eye Contact: This product is an eye irritant. Exposure to the eye may cause symptoms which include a burning sensation, tearing, redness and swelling.

    Ingestion: No adverse health effects are expected if a small amount of this product is accidentally ingested.

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Effects of Long-Term (Chronic) Exposure: This product contains ingredients which have been known to cause skin sensitization in some people. Sensitization may occur after prolonged or repeated exposures to this product. Prolonged contact with skin may defat tissue causing dermititis or aggravate existing skin problems.

Medical Conditions Aggravated By Exposure: Persons susceptable to skin problems may find that the use of this product will cause increased symptoms of existing skin problems.

4.3 Indication of any immediate medical attention and special treatment needed

In the event of an allergic reaction, immediate medical help is required. Allergic reactions may result in various health effects including respiration.

5. Fire Fighting Measures

  1. 5.1  Extinguishing Media
    Suitable extinguishing media: Dry chemical, carbon dioxide, water spray, foam, or water fog.

  2. 5.2  Special hazards arising from mixture: Carbon dioxide, carbon monoxide, oxides of nitrogen, undetermined organic compounds in acrid smoke.

  3. 5.3  Advice for firefighters: Do not enter fire area without proper protection. Fight fire from a safe distance, upwind. Use of water may be ineffective due to low solubility. If water is used, direct fine spray or fog at fire to cool and extinguish flames.

  4. 5.4  Further Information:
    Sensitivity to Impact: No

    Sensitivity to Static Discharge: No

    NATIONAL FIRE PROTECTION ASSOCIATION (NFPA) HAZARD INDEX:

    HEALTH: 3 FLAMMABILITY: 1 REACTIVITY: 0

    6. Accidental Release Measures

6.1 Personal precautions, protective equipment and emergency procedures

Respiratory Protection: Vapours will be generated particularly if product is atomized, or heated. If used or sprayed in an enclosed area, at a minimum use a NIOSH approved organic vapour respirator. When cartridge type respirators are used, ensure that the cartridges are changedfrequently according to the manufacturer’s recommendations. Respirator selection must be done by a qualified person and be based upon a risk assessment of the work activities and exposure levels. Respirators must be fit tested and users must be clean shaven where the respirator seals to face. Exposure must be kept at or below the applicable exposure limits and the maximum use concentration of the respirator must not be exceeded.

Skin protection: Depending upon the conditions of use, protective gloves and clothing to prevent skin contact.

Eye and Face Protection: Chemical splash goggles and/or face shield must be worn when a possibility exists for eye contact due to spashing or spraying liquid. Contact lenses should not be worn.

Footwear: No specific recommendation.

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Other: Emergency eyes wash fountains should be available in vicinity of use. At minimum, an eye lavage kit should be kept on hand.

  1. 6.2  Environmental precautions

    Ensure that any release of this material is contained to prevent leakage into waterways and sanitary sewers.

  2. 6.3  Methods and materials for containment and cleanup
    Remedial Measures: Wash spill area with strong detergent and water solution, rinse with minimal

    water, if possible.

    Large Spills: For large spills, dike area and prevent leakage into waterways or sanitary sewers. Recover using spark proof equipment and store in approved vented containers for re-use or disposal.

    Small Spills: Small spills may be absorbed on an inert medium such as vermiculite or clay, then sweep into vented disposal containers.

  3. 6.4  Referencetoothersections

    For disposal, see section 13

    7. Handling and Storage

  1. 7.1  Precautions for safe handling
    Handling Procedures: Wear proper protective equipment when handling this material. Only use

    non-sparking tools when handling this material.

  2. 7.2  Conditions for safe storage, including incompatibilities

    Storage: Store indoors in a well ventilated area where the storage temperature can be maintained between 1oC and 38oC. Storage above 38oC will result in reduced product life. Store in tightly closed containers away from heat, sparks, open flame, strong oxidizers, radiation and other initiators. Prevent contamination with foreign materials, including moisture.

  3. 7.3  Specific end use(s)

    No other uses except those mentioned in Section 1.2

    8. Exposure Controls, Personal Protection

8.1 Control parameters
Components with workplace control parameters

Hydroxypropyl Methacrylate, component 2-Methylpropenic Acid, (CAS No. 79-41-4) ACGIH TLV TWA: 20 ppm, eye and skin irritation,

component Methyloxirane, (CAS No. 75-56-9) ACGIH TLV-TWA: 2 ppm

4-Methoxyphenol, (CAS No 150-76-5), ACGIH TLV TWA : 5 mg/m3, eye irritation, skin damage 1-Methyl-2-pyrrolidone, (CAS No 872-50-4), WEEL, Workplace Environmental Exposure Levels,

10 ppm

Note: Silica and titanium dioxide have respiratory exposure controls, but since these components are bound into the product and are not capable of becoming airborne, exposure controls need not be listed.

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8.2 Exposure controls

Engineering Controls: When using indoors, ensure adequate ventilation by using local exhaust. Mechanical ventilation is recommended for all indoor situations to control fugitive emissions. Electrical and mechanical equipment should be explosion proof.

Respiratory Protection: Vapours will be generated particularly if product is atomized, or heated. If used or sprayed in an enclosed area, at a minimum use a NIOSH approved organic vapour respirator. When cartridge type respirators are used, ensure that the cartridges are changedfrequently according to the manufacturer’s recommendations. Respirator selection must be done by a qualified person and be based upon a risk assessment of the work activities and exposure levels. Respirators must be fit tested and users must be clean shaven where the respirator seals to face. Exposure must be kept at or below the applicable exposure limits and the maximum use concentration of the respirator must not be exceeded.

Skin protection: Depending upon the conditions of use, protective gloves and clothing to prevent skin contact.

Eye and Face Protection: Chemical splash goggles and/or face shield must be worn when a possibility exists for eye contact due to spashing or spraying liquid. Contact lenses should not be worn.

Footwear: No specific recommendation.
Other: Emergency eyes wash fountains should be available in vicinity of use. Control of environmental exposure
Prevent further leakage or spillage, if safe to do so. Do not let product enter drains.

9. Physical and Chemical Properties

9.1 Information on basic physical and chemical properties

10.1

9.2 Other safety information: None
10. Stability and Reactivity

Reactivity

Appearance: Odour:
Odour Threshold: pH:

Melting Point/Freezing Point: Initial Boiling Point:
Flash Point:
Evaporation Rate: Flammability:

Upper Explosion Limit: Lower Explosion Limit: Vapour Pressure: Vapour Density: Relative Density: Solubility:

Partition Coefficient: Autoignition Temperature: Decomposition Temperature: Viscosity:
Explosive Properties: Oxidizing Properties:

Viscous liquid, various colours Characteristic acrylic odour Not available
Not applicable

0°C 131 oC

>93.3 oC
Negligible
Not flammable
No data
No data
< 0.01 @ 20oC
No data
1.03- 1.18 @ 25oC (water=1)
Negligible in water
Not available
No data
No data
No data
Not explosive. Not expected to be sensitive to electrostatic discharge. No data

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Product may become reactive if inhibitor is depleted.

  1. 10.2  Chemical Stability

    Stable as supplied.

  2. 10.3  Possibility of hazardous reactions

    High temperatures, inhibitor depletion, accidental impurities, or exposure to radiation or oxidizers may initiate spontaneous polymerization, generating heat and pressure. Closed containers may rupture during hazardous polymerization.

  3. 10.4  Conditions to avoid

    Exposure to heat, light and moisture.

  4. 10.5  Incompatible materials

    Keep away from strong oxidizers and moisture.

  5. 10.6  Hazardous decomposition products

    Carbon monoxide, carbon dioxide and various oxides of nitrogen.

11. Toxicological Information

11.1 Information on toxicological effects

Note to reader: We do NOT test our products on animals. In compliance with current SDS preparation requirements, the values listed are published values for generic ingredients with known animal toxicity.

Acute toxicity Component

Di-Hema Trimethylhexyl Dicarbamate, (CAS No. Proprietory) (EINECS No. None)
2-Hydroxyethyl Methacrylate (HEMA), (CAS No. 868-77-9)
( EINECS No. 212-782-2)

Hydroxypropyl Methacrylate, (CAS No. 27813-02-1)
(EINECS No. 248-666-3)
Trimethylbenzoyl Diphenylphosphine Oxide, (CAS No. 75980-60-8) (EINECS No. 278-355-8)

4- Methoxyphenol (p- Hydroxyanisole), (CAS No. 150-76-5) (EINECS No. 205-769-8)
PEG-4 Dimethylacrylate, (CAS No 109-17-1)
(EINECS No. 203-653-1)

1-Methyl-2-pyrrolidone, (CAS No 872-50-4) (EINECS No. 212-828-1)
Titanium Dioxide, CAS No. 13463-67-7 EINECS No. 236-675-5

Silica, CAS No. 7631-86-9 EINECS No. 231-545-4

LD50

>5000 mg/kg (oral/rat)

5564 mg/kg (oral/rat)
>3000 mg/kg (dermal/rabbit)

11,200 mg/kg (oral/rat)

>5000 mg/kg (oral/rat) >2000 mg/kg (dermal/rabbit)

N/av
>3000 mg/kg (oral/rat)

3914 mg/kg (oral/rat)
8000 mg/kg (dermal/rabbit) >25,000 mg/kg (oral/rat) >10,000 mg/mg (dermal/rabbit) 3160 mg/kg (oral/rat)

LC50

N/av N/av N/av N/av

N/av N/av

LDLO >5100 ppm (inh, rat/4h) >6820 mg/m3

N/av

                         

ABBREVIATION KEY: N/p: not published, N/d: not determined, N/ap: not applicable, N/av: not available Skin corrosion/irritation

Components of this mixture may cause skin irritation, H315, Category 2, Warning

Serious eye damage/eye irritation

Components of this mixture may cause eye irritation, H319, Category 2A, Warning

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Respiratory or skin sensitization

Components of this mixture may cause skin sensitization, H317, Category 1, Warning

Germ Cell Mutagenicity

Components in this mixture suspected of causing genetic defects, H341, Category 2, Warning

Carcinogenicity

Not classifiable as a human carcinogen. Titanium dioxide is present in the formulation but is not in a respirable form and cannot become airborne.

Reproductive toxicity

Components in this mixture are suspected of damaging fertility or the unborn child, H361, Category 2, Warning

Specific Target Organ Toxicity – Single exposure

Components of this mixture may cause respiratory irritation, H335, Category 3, Warning

Specific Target Organ Toxicity – Repeated exposure

No information available

Aspiration Hazard

No information available

Additional information

None

12.1 Toxicity To fish:

12.

Ecological Information

No data available

flow through test Fathead Minnow 227mg/l – 96 hour No data available
LC50: rainbow trout – 28.5 mg/l – 96 hour
10 – 100 mg/l

No data available

345 mg/L/72hr (Green algae) > 97 mg/L/72hr (Green algae) No data available
10 – 100 mg/l72 hr

No data available

380 mg/l
>140 mg/l
No data available 10 – 100 mg/l

Di-Hema Trimethylhexyl

Dicarbamate
2-Hydroxyethyl methacrylate Hydroxypropyl methacrylate 4-Methoxyphenol Trimethylbenzoyl

diphenylphosphine oxide

To algae:

Di-Hema Trimethylhexyl

Dicarbamate
2-Hydroxyethyl methacrylate Hydroxypropyl methacrylate 4-Methoxyphenol Trimethylbenzoyl

diphenylphosphine oxide

To daphnia:

Di-Hema Trimethylhexyl Dicarbamate
2-Hydroxyethyl methacrylate Hydroxypropyl methacrylate 4-Methoxyphenol Trimethylbenzoyl

diphenylphosphine oxide

12.2 Persistence and degradability

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12.3 12.4 12.5

12.6

13.1

2-Hydroxyethyl methacrylate (HEMA) and Hydroxypropyl methacrylate (HPMA) are considered to be readily biodegradable.
Trimethylbenzoyl diphenylphosphine oxide is considered to be poorly biodegradable.

Isobornyl acrylate. Isobornyl acrylate is not considered to be readily biodegradable.

Bioaccumulative potential

No data available

Mobility in soil

No data available

Results of PBT and vPvB assessment

Not conducted

Other adverse effects

No data available

13. Disposal Considerations

Waste treatment methods

Product:

Review federal, provincial or state, and local government requirements prior to disposal. Store material for disposal as indicated in Storage Conditions. Disposal by controlled incineration or by secure land fill may be acceptable.

Contaminated packaging

Dispose as above.

14. Transport Information

Transport classification for Shine On, Matte On, Black On, White On Transport of Dangerous Goods (TDG and CLR): Not regulated

United States Department of Transport (49CFR): Not regulated International Air Transport Association (IATA): Not regulated International Maritime Organization (IMO): Not regulated

15. Regulatory Information

CANADIAN FEDERAL REGULATIONS:
CEPA, DOMESTIC SUBSTANCES LIST: Listed

UNITED STATES – FEDERAL REGULATIONS:
TOXIC SUBSTANCES CONTROL ACT (TSCA): All components are listed in the inventory.

CALIFORNIA Proposition 65, Safe Drinking Water and Toxicity Enforcement Act, 1986:

Methyloxirane, component CAS No 75-56-9 of Hydroxypropyl Methacrylate

OSHA, 29 CFR 1910, Subpart Z: Meets criteria for a hazardous substance.
CERCLA, 40 CFR 302: No ingredient listed
SARA 302, 40 CFR 355: Methyloxirane, component CAS No 75-56-9, Rev Date: 2008-11-03 SARA 313, 40 CFR 372: Methyloxirane, component CAS No 75-56-9, Rev Date: 2008-11-03

 

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SARA 311/312, 40 CFR 370: Immediate (Acute) Health, Delayed (Chronic) Health Massachusetts Right to Know: 4- Methoxyphenol (p- Hydroxyanisole), Methyloxirane,

New Jersey Right to Know: 4- Methoxyphenol (p- Hydroxyanisole), Methyloxirane, 2-Hydroxyethyl Methacrylate (HEMA), Trimethylbenzoyl Diphenylphosphine Oxide

Pennsylvania Right to Know: 4- Methoxyphenol (p- Hydroxyanisole), Methyloxirane, 2-Hydroxyethyl Methacrylate (HEMA), Trimethylbenzoyl Diphenylphosphine Oxide

16. Other Information

Original Preparation Date: March 17, 2017

Prepared by: KJ Pearson, West Vancouver, BC, V7W 1P3

Disclaimer: This Safety Data Sheet (SDS) was prepared using information provided by CCINFO, ingredient supplier SDS and other relevant sources. This product has been classified using weight of evidence, expert judgment and previous testing as per Part 1.3 of the Fifth Edition of The Globally Harmonized System of Classification and Labelling of Chemicals (GHS). The information in this SDS is offered for your consideration and guidance when exposed to this product. Haigh Industries Inc. expressly disclaims all expressed or implied warranties and assumes no responsibilities for the accuracy or completeness of the data contained herein. The data in this SDS does not apply to use with any other product or in any other process.

This Safety Data Sheet may not be changed, or altered in any way without the expressed knowledge and permission of Haigh Industries Inc.

Revisions: None

Haigh Industries Inc. - 11 - March 17, 2017